淀粉浓度和灌装初始温度对罐头淀粉类食品冷区变化的数值研究

A. R. Nedamani, A. Ziaiifar, M. Parvini, M. Kashaninejad, Y. Maghsoudlou
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Starchmaybe naturally exist in foods ormay be added to food formulations as an additive to create the consistency, filler, volumeproviders, emulsionstabilizer and etc. However, during thermal processing of foodscontaining high amounts of starch, complexstructural changes occur which leads to viscosity increases. These changes aredue to structural changes of starch during gelatinization; such as irreversible swelling of the starch granules, melting of starchcrystals, leaking of starch granule compound. Depending on thetype of starch and its concentration, the final product can bean aqueous solution or agel structure. Increasing in starch viscosity after gelatinization leads to decrease in heating rate, but with the advancement of heating time, when most granule swelling occurs, and the granules are being disrupted and the viscosity is reduced. This leads to increase the heating rate. This dual behavior of starch dispersion viscosity, leads to break in heating curve. Such solutions are named broken heating curve foods.The aim of this study was numerical simulation of the effect of starch concentration and initial temperature on heat transfer rate of starch dispersion during static sterilization with COMSOL software. Materials and methods:To prepare 100ml of 3.5 and 5% starch dispersion, 3.5 and 5 g starch was dissolved in 96.5 and 95 ml distilled water at 24.7C, respectively. The solution was then heated at 50C for 10 min to avoid sedimentation during the heat process. Samples were filled at 50 and 75C initial temperatures. In each can (9.9×10.1cm), T- type thermocouple was placedin one-third length from the bottom. All measurements were performed in triplicates. The 8-port data logger (Pico-TC08, England) and related software (PicoLog) were used to record the temperature data with 10s intervals.The full filled cans (without headspace) were statically heated in vertical position with no rotation. Numerical solutions of the governing equations were performed by COMSOL Multiphasics 4.2b software. A BDF method for time stepping and Backward Euler to time discretization were used. The system used to run the test and solve the equation was Intel VR CoreTM i5CPU M 460 @ 1.70 GHz and 6GB RAM. Numerical simulation of COMSOL software include spairing two physical phenomena: heat transfer and fluidflow. Since the system was cylindrical shaped can contain food with natural convection, non-isothermal laminar flow equationswere used. For this problem, one geometry and two domains were defined. The governing equations for non-isothermal laminar flow for domains were defined. Since in thermal diffusion analysis, the formula methods are more correct than empirical methods, formula methods were used in this study for calculating j and f. The accuracy of these calculations was evaluated using CFD. Parameter - f is the slope of heating curve. Jhindex, as a dimensionless correction factor. 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引用次数: 2

摘要

制作罐头是保存食物最有效的方法。淀粉类食品包括粥等主要食品原料。这些食品由于对高剪切速率敏感,在旋转蒸馏器中使用,因此质地分解,通常在静态蒸馏器中消毒。在这些产品中,破碎加热行为、顶空和初始温度对传热速率和冷区位置有重要影响。在含淀粉的食品中可以看到热曲线中的热断裂现象,其本质上与淀粉结构的糊化和破坏有关。淀粉可能自然存在于食品中,也可能作为添加剂添加到食品配方中,以创造稠度、填充剂、体积提供剂、乳化稳定剂等。然而,在含有大量淀粉的食品的热加工过程中,会发生复杂的结构变化,从而导致粘度增加。这些变化是由于淀粉在糊化过程中的结构变化;如淀粉颗粒的不可逆膨胀、淀粉晶体的熔化、淀粉颗粒化合物的泄漏等。根据淀粉的种类和浓度,最终产物可以是水溶液或凝胶状结构。糊化后淀粉粘度的增加导致加热速率的降低,但随着加热时间的延长,大部分颗粒发生膨胀,颗粒被打乱,粘度降低。这导致升温速率增加。这种淀粉分散粘度的双重特性,导致了加热曲线的断裂。这样的溶液被称为加热曲线断裂食品。采用COMSOL软件对静态灭菌过程中淀粉浓度和初始温度对淀粉分散传热速率的影响进行了数值模拟。材料与方法:制备3.5、5%淀粉分散体100ml, 3.5、5 g淀粉分别溶于96.5、95 ml蒸馏水中,浓度为24.7℃。然后将溶液在50℃下加热10分钟,以避免在加热过程中沉淀。样品在50和75℃初始温度下填充。在每个罐(9.9×10.1cm), T型热电偶被放置在距离底部三分之一的长度。所有测量均为三次。使用8端口数据记录仪(Pico-TC08,英国)和相关软件(PicoLog)每隔10s记录一次温度数据。装满的罐头(没有顶空)在垂直位置静态加热,不旋转。采用COMSOL Multiphasics 4.2b软件对控制方程进行数值求解。采用BDF法进行时间步进,并采用向后欧拉法进行时间离散。用于运行测试和求解方程的系统是Intel VR CoreTM i5CPU M 460 @ 1.70 GHz和6GB RAM。COMSOL软件的数值模拟包括传热和流体流动两种物理现象。由于该系统是圆柱形的,可以容纳自然对流的食物,因此使用了非等温层流方程。对于这个问题,定义了一个几何和两个域。定义了区域非等温层流的控制方程。由于在热扩散分析中,公式方法比经验方法更准确,因此本研究采用公式方法计算j和f,并利用CFD对计算的准确性进行了评价。参数- f为加热曲线的斜率。jhinindex,作为无量纲校正因子。结果与讨论:结果表明,冷区在罐底的十分之一附近。在两种产品的初始温度下,将产品中淀粉的浓度从3.5%变化到5%会导致更长的加热时间。罐底十分之一处的热处理时间增加幅度大于罐底的三分之一。分散体达到静态温度的时间也随分散体中淀粉的浓度而变化。在静态温度下,5%淀粉分散体在加热结束时的温差比3.5%淀粉分散体大得多。较高的淀粉浓度导致在罐底三分之一处f (fh系数表示加热过程在加热曲线中移动一个周期所需的时间,可由热曲线线性部分的斜率计算)下降,而在罐底十分之一处f增加。这种行为可能与由于温度升高较快,淀粉糊化在三分之一罐底比十分之一罐底发生得早有关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
NUMERICAL STUDY OF STARCH CONCENTRATION AND FILLING INITIAL TEMPERATURE ON COLD AREA CHANGES IN CANNED STARCH-BASED FOOD
Introduction: Canning is the most effective way to food preservation. Starch- based foods include the major food materials such as porridges. These foods due to sensitivity to high shear rates used in rotary retorts and thus texture decomposition, usually sterilized in static retorts. Broken heating behavior, can headspace and initial temperature have important role on heat transfer rate and the position of cold area in these products. Heat breaking phenomena in the thermal curve, which can be seen in foods containing starch, is essentially related to gelatinization and destroying of starchgelstructure. Starchmaybe naturally exist in foods ormay be added to food formulations as an additive to create the consistency, filler, volumeproviders, emulsionstabilizer and etc. However, during thermal processing of foodscontaining high amounts of starch, complexstructural changes occur which leads to viscosity increases. These changes aredue to structural changes of starch during gelatinization; such as irreversible swelling of the starch granules, melting of starchcrystals, leaking of starch granule compound. Depending on thetype of starch and its concentration, the final product can bean aqueous solution or agel structure. Increasing in starch viscosity after gelatinization leads to decrease in heating rate, but with the advancement of heating time, when most granule swelling occurs, and the granules are being disrupted and the viscosity is reduced. This leads to increase the heating rate. This dual behavior of starch dispersion viscosity, leads to break in heating curve. Such solutions are named broken heating curve foods.The aim of this study was numerical simulation of the effect of starch concentration and initial temperature on heat transfer rate of starch dispersion during static sterilization with COMSOL software. Materials and methods:To prepare 100ml of 3.5 and 5% starch dispersion, 3.5 and 5 g starch was dissolved in 96.5 and 95 ml distilled water at 24.7C, respectively. The solution was then heated at 50C for 10 min to avoid sedimentation during the heat process. Samples were filled at 50 and 75C initial temperatures. In each can (9.9×10.1cm), T- type thermocouple was placedin one-third length from the bottom. All measurements were performed in triplicates. The 8-port data logger (Pico-TC08, England) and related software (PicoLog) were used to record the temperature data with 10s intervals.The full filled cans (without headspace) were statically heated in vertical position with no rotation. Numerical solutions of the governing equations were performed by COMSOL Multiphasics 4.2b software. A BDF method for time stepping and Backward Euler to time discretization were used. The system used to run the test and solve the equation was Intel VR CoreTM i5CPU M 460 @ 1.70 GHz and 6GB RAM. Numerical simulation of COMSOL software include spairing two physical phenomena: heat transfer and fluidflow. Since the system was cylindrical shaped can contain food with natural convection, non-isothermal laminar flow equationswere used. For this problem, one geometry and two domains were defined. The governing equations for non-isothermal laminar flow for domains were defined. Since in thermal diffusion analysis, the formula methods are more correct than empirical methods, formula methods were used in this study for calculating j and f. The accuracy of these calculations was evaluated using CFD. Parameter - f is the slope of heating curve. Jhindex, as a dimensionless correction factor. Results and discussion: The results showed that thecold area is near theone-tenth ofcans bottom. Inboth product initial temperatures, varying the concentration of the starch in product from 3.5 to 5% leads to longer heating time. The increase in the thermal process time at one-tenth of can bottom is more than one-third of can bottom. The time which the dispersion reaches to static temperature also changes with starch concentration in dispersion. The temperature difference in 5% starch dispersion at static temperature at the end of heating process is more considerable than 3.5% starch dispersion. Higher starch concentration induces a decrease in f (The fh coefficient represents thetime required to move heating process one cycle in heating curve and it can be calculated from the slope of the linear part of heat curve) at one-third of can bottom while an increase in f at one-tenth of can bottom. This behavior can be related to the fact that the starch gelatinization takes place earlier in one-third of can bottom than one- tenth due to the faster increase in temperature.
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