准分子激光烧蚀制备Fe-N薄膜

T. Yoshitake;M. Ohkoshi;K. Tsushima
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引用次数: 4

摘要

使用脉冲KrF准分子激光器(波长248nm,脉冲宽度27ns)在室温下在玻璃基板上沉积Fe-N膜。膜的组成和结构取决于环境N2压力、激光脉冲能量和重复率。为了了解准分子激光烧蚀Fe产生的发光烧蚀颗粒与环境N2气体之间的相互作用,利用高速成帧条纹相机和时间分辨发射光谱研究了烧蚀羽流的动力学。观察到烧蚀颗粒的两种不同成分。其中一个由平均速度超过100公里/秒的球形羽流组成,在激光照射下观察了约300纳秒。另一个由最大速度为22 km/s的柱状羽流组成,观测时间为1至10μs。Fe自由基的速度取决于N2压力,N2压力有助于Fe-N膜的形成。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Fe-N Thin Films Prepared by Excimer Laser Ablation
Fe-N films were deposited on glass substrates at room temperature using a pulsed KrF excimer laser (wavelength 248 nm, pulse width 27 ns). The film composition and structure depend on the ambient N 2 pressure, the laser pulse energy, and the repetition rate. In order to understand the interaction between light-emitting ablated particles produced by excimer laser ablation of Fe and ambient N 2 gas, the dynamics of ablated plumes were investigated by means of a high-speed framing streak camera and time-resolved emission spectroscopy. Two distinct components of ablated particles were observed. One consisted of a spherical plume with an average velocity of over 100 km/s, which was observed for about 300 ns from the laser irradiation. The other consisted of a columnar plume with a maximum velocity of 22 km/s, which was observed for 1 to 10 μs. The velocity of the Fe radicals depends on the N 2 pressure, which contributes to formation of the Fe-N film.
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