基于低聚环氧氯丙烷和哌嗪的离子交换流体材料

K. E. Varlan, Svetlana A. Plotichkina, Aleksandra L. Kuzmenko
{"title":"基于低聚环氧氯丙烷和哌嗪的离子交换流体材料","authors":"K. E. Varlan, Svetlana A. Plotichkina, Aleksandra L. Kuzmenko","doi":"10.15421/081413","DOIUrl":null,"url":null,"abstract":"The film materials with ion-exchanged properties on the basis of the polymer, obtained by condensation of oligoepichlorohydrined epoxide and piperazine with the subsequent chemical modification have been synthesized. Compounds which have different thermodynamic affinity with the polymer and each other have been used as modifiers. It has been shown that the possibility of overcoming the lack of compatibility of the components by selection of the order of their combination. The result of the combination can be predicted by the Hildebrand parameter values of the ingredients, intermediate products and prepolymers based on them. The properties of synthesized materials can be adjusted by selection of combinations of chemical modifiers: toluilenediisocyanate, epoxyed soybean oil and tetraethoxysilane.","PeriodicalId":31165,"journal":{"name":"Visnik Dnipropetrovs''kogo Universitetu Seria Himia","volume":"22 1","pages":"71-75"},"PeriodicalIF":0.0000,"publicationDate":"2014-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Іонообмінні плівкові матеріали на основі олігоепіхлоргідринового епоксиду і піперазину\",\"authors\":\"K. E. Varlan, Svetlana A. Plotichkina, Aleksandra L. Kuzmenko\",\"doi\":\"10.15421/081413\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The film materials with ion-exchanged properties on the basis of the polymer, obtained by condensation of oligoepichlorohydrined epoxide and piperazine with the subsequent chemical modification have been synthesized. Compounds which have different thermodynamic affinity with the polymer and each other have been used as modifiers. It has been shown that the possibility of overcoming the lack of compatibility of the components by selection of the order of their combination. The result of the combination can be predicted by the Hildebrand parameter values of the ingredients, intermediate products and prepolymers based on them. The properties of synthesized materials can be adjusted by selection of combinations of chemical modifiers: toluilenediisocyanate, epoxyed soybean oil and tetraethoxysilane.\",\"PeriodicalId\":31165,\"journal\":{\"name\":\"Visnik Dnipropetrovs''kogo Universitetu Seria Himia\",\"volume\":\"22 1\",\"pages\":\"71-75\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-12-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Visnik Dnipropetrovs''kogo Universitetu Seria Himia\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.15421/081413\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Visnik Dnipropetrovs''kogo Universitetu Seria Himia","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15421/081413","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

以低聚环氧氯丙烷与哌嗪缩合为原料,经化学改性,合成了具有离子交换性能的薄膜材料。采用与聚合物具有不同热力学亲和关系的化合物作为改性剂。研究表明,通过选择组合的顺序,可以克服各组分相容性不足的问题。结合的结果可以通过原料、中间产物和基于它们的预聚物的希尔德布兰德参数值来预测。通过选择甲苯二异氰酸酯、环氧大豆油和四乙氧基硅烷等化学改性剂的组合来调整合成材料的性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Іонообмінні плівкові матеріали на основі олігоепіхлоргідринового епоксиду і піперазину
The film materials with ion-exchanged properties on the basis of the polymer, obtained by condensation of oligoepichlorohydrined epoxide and piperazine with the subsequent chemical modification have been synthesized. Compounds which have different thermodynamic affinity with the polymer and each other have been used as modifiers. It has been shown that the possibility of overcoming the lack of compatibility of the components by selection of the order of their combination. The result of the combination can be predicted by the Hildebrand parameter values of the ingredients, intermediate products and prepolymers based on them. The properties of synthesized materials can be adjusted by selection of combinations of chemical modifiers: toluilenediisocyanate, epoxyed soybean oil and tetraethoxysilane.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
审稿时长
14 weeks
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信