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引用次数: 17
摘要
Johnson Matthey，催化和手性技术，2001 Nolte Drive, West Deptford, New Jersey 08066, USA Email: colactj@jmusa.com钯催化交叉偶联在实验室和工业规模上对许多有机分子的合成都具有重要意义。目前，Johnson Matthey公司已经开发了一系列商用预成型(R3P)2Pd(0)催化剂。本文综述了钯催化剂在各种交叉偶联反应中的一些独特和高选择性的应用，包括碳卤化反应、芳酰氯根岸偶联和无铜Sonogashira偶联等新型反应。
Commercial Development of Palladium(0) Catalysts for Highly Selective Cross-Coupling Reactions
Johnson Matthey, Catalysis and Chiral Technologies, 2001 Nolte Drive, West Deptford, New Jersey 08066, USA Email: colactj@jmusa.com Palladium-catalysed cross-coupling has huge importance for the synthesis of many organic molecules at both laboratory and industrial scale. A range of commercially available preformed (R3P)2Pd(0) catalysts have now been developed and are available from Johnson Matthey. Some unique and highly selective applications of these palladium catalysts for various cross-coupling reactions, including novel reactions such as carbohalogenation reactions, Negishi coupling of aryl chlorides and copper-free Sonogashira coupling, are highlighted in this review.
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