Sharafat Ali , Jacek Ryl , Abbas Saeed Hakeem , Katarzyna Grochowska , Natalia Anna Wójcik
{"title":"富铝Ca-Al-Si-O-N玻璃的结构和热性能研究","authors":"Sharafat Ali , Jacek Ryl , Abbas Saeed Hakeem , Katarzyna Grochowska , Natalia Anna Wójcik","doi":"10.1016/j.progsolidstchem.2023.100414","DOIUrl":null,"url":null,"abstract":"<div><p><span>In this paper, we investigate the structure and thermal properties<span> of aluminum-rich transparent Ca–Al–Si–O–N glasses. The obtained glasses were prepared by a traditional melt-quenching technique at 1650 °C using AlN as the nitrogen source. The obtained glasses have a </span></span><em>n</em><sub>Al</sub>/<em>n</em><sub>Si</sub><span>>1 and contain up to 17 eq.% of N. The structure of the glasses was characterized by X-ray diffraction, X-ray photoelectron spectroscopy, infrared, and Raman spectroscopy<span> techniques. The structure analysis shows a higher preference for Si–N bond formation relative to Al–N bond formation and aluminum is predominately present in tetrahedral coordination as AlO</span></span><sub>4</sub><span> units. The thermal properties of samples were studied by differential thermal analysis and the obtained glass transition temperature ranges from 875 °C to 950 °C, and is primarily influenced by the N content. The glass stability can be correlated with both the N and Al contents in the studied glasses. It is improved due to the increased degree of network polymerization by the incorporation of nitrogen.</span></p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"71 ","pages":"Article 100414"},"PeriodicalIF":9.1000,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigation of the structural and thermal properties of aluminum-rich Ca–Al–Si–O–N glasses\",\"authors\":\"Sharafat Ali , Jacek Ryl , Abbas Saeed Hakeem , Katarzyna Grochowska , Natalia Anna Wójcik\",\"doi\":\"10.1016/j.progsolidstchem.2023.100414\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span>In this paper, we investigate the structure and thermal properties<span> of aluminum-rich transparent Ca–Al–Si–O–N glasses. The obtained glasses were prepared by a traditional melt-quenching technique at 1650 °C using AlN as the nitrogen source. The obtained glasses have a </span></span><em>n</em><sub>Al</sub>/<em>n</em><sub>Si</sub><span>>1 and contain up to 17 eq.% of N. The structure of the glasses was characterized by X-ray diffraction, X-ray photoelectron spectroscopy, infrared, and Raman spectroscopy<span> techniques. The structure analysis shows a higher preference for Si–N bond formation relative to Al–N bond formation and aluminum is predominately present in tetrahedral coordination as AlO</span></span><sub>4</sub><span> units. The thermal properties of samples were studied by differential thermal analysis and the obtained glass transition temperature ranges from 875 °C to 950 °C, and is primarily influenced by the N content. The glass stability can be correlated with both the N and Al contents in the studied glasses. It is improved due to the increased degree of network polymerization by the incorporation of nitrogen.</span></p></div>\",\"PeriodicalId\":415,\"journal\":{\"name\":\"Progress in Solid State Chemistry\",\"volume\":\"71 \",\"pages\":\"Article 100414\"},\"PeriodicalIF\":9.1000,\"publicationDate\":\"2023-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Progress in Solid State Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0079678623000250\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Solid State Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0079678623000250","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Investigation of the structural and thermal properties of aluminum-rich Ca–Al–Si–O–N glasses
In this paper, we investigate the structure and thermal properties of aluminum-rich transparent Ca–Al–Si–O–N glasses. The obtained glasses were prepared by a traditional melt-quenching technique at 1650 °C using AlN as the nitrogen source. The obtained glasses have a nAl/nSi>1 and contain up to 17 eq.% of N. The structure of the glasses was characterized by X-ray diffraction, X-ray photoelectron spectroscopy, infrared, and Raman spectroscopy techniques. The structure analysis shows a higher preference for Si–N bond formation relative to Al–N bond formation and aluminum is predominately present in tetrahedral coordination as AlO4 units. The thermal properties of samples were studied by differential thermal analysis and the obtained glass transition temperature ranges from 875 °C to 950 °C, and is primarily influenced by the N content. The glass stability can be correlated with both the N and Al contents in the studied glasses. It is improved due to the increased degree of network polymerization by the incorporation of nitrogen.
期刊介绍:
Progress in Solid State Chemistry offers critical reviews and specialized articles written by leading experts in the field, providing a comprehensive view of solid-state chemistry. It addresses the challenge of dispersed literature by offering up-to-date assessments of research progress and recent developments. Emphasis is placed on the relationship between physical properties and structural chemistry, particularly imperfections like vacancies and dislocations. The reviews published in Progress in Solid State Chemistry emphasize critical evaluation of the field, along with indications of current problems and future directions. Papers are not intended to be bibliographic in nature but rather to inform a broad range of readers in an inherently multidisciplinary field by providing expert treatises oriented both towards specialists in different areas of the solid state and towards nonspecialists. The authorship is international, and the subject matter will be of interest to chemists, materials scientists, physicists, metallurgists, crystallographers, ceramists, and engineers interested in the solid state.