含或不含两种不同钙源的碱活性陶瓷废料

IF 1.9 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Sayieda R. Zedan, M. Mohamed, D. Ahmed, Aya H. Mohammed
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引用次数: 6

摘要

. 以不同浓度的氢氧化钠(NaOH)和液态硅酸钠(LSS)为原料,对陶瓷废料(AACW)进行碱活化制备地聚合物树脂。为了制备地聚合物水泥,AACW分别用10%和30%重量(wt.,)的混凝土废料(CoW)以及10%和30%重量(wt.,)的磨碎的高炉矿渣(GGBFS)代替。结果表明,AACW的抗压强度随活化剂含量的增加而增加,可达15:15 wt., % NaOH: LSS;所有AACW硬化试样分别以3:3 (MC6)、6:6 (MC12)、12:12 (MC24)和15:15 wt., % (MC30) NaOH激活:LSS在水中固化24小时后被破坏。MC18混合料具有较高的水固化电阻率。结果还表明,将含有9:9 wt., % NaOH: LSS (MC18)的AACW替换为10 (MCCo10)和30 (MCCo30) wt., % CoW的AACW在养护的各个阶段都降低了抗压强度。相比之下,MCCo10混合物的化学结合水含量低于MC18混合物。与MC18和MCCo10混合物相比,MCCo30混合物显示出更高的化学组合含水量。所有含GGBFS的AACW混合物(MCS10和MCS30)的抗压强度和化学结合水均高于不含GGBFS的AACW (MC18)。随着GGBFS含量的增加,化学结合水也随之增加。x射线衍射(XRD)证实,随着CoW含量的增加,结晶度增大。相反,用GGBFS代替AACW会增加非晶性。红外光谱(FTIR)证实,由于连续水化产物的形成,GGBFS比CoW具有更高的反应活性,从而增强了扫描电镜(SEM)观察到的微观结构的压实性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Alkali activated ceramic waste with or without two different calcium sources
. The aim of this investigation is to prepare geopolymer resin by alkali activation of ceramic waste (AACW) with different sodium hydroxide (NaOH) and liquid sodium silicate (LSS) concentrations. In order to prepare geopolymer cement, AACW was replaced by 10 and 30 % by weight (wt.,) of concrete waste (CoW) as well as 10 and 30 wt., % ground granulated blast-furnace slag (GGBFS). The results showed that, the compressive strength of AACW increases with the increase of activator content up to 15:15 wt., % NaOH: LSS. All AACW hardened specimens activated by 3:3 (MC6), 6:6 (MC12), 12:12 (MC24) and 15:15 wt., % (MC30) NaOH: LSS destroyed when cured in water for 24h. The MC18 mix showed higher resistivity to water curing. The results also showed that, the replacement of AACW containing 9:9 wt., % NaOH: LSS (MC18) by 10 (MCCo10) and 30 (MCCo30) wt., % CoW decreased the compressive strength at all ages of curing. In contrast, the MCCo10 mix showed the lower chemically combined water content compared to MC18 mix. The MCCo30 mix showed the higher chemically combined water content compared to MC18 and MCCo10 mixes. The compressive strength and chemically combined water of all AACW mixes containing GGBFS (MCS10 and MCS30) were higher than those of AACW with no GGBFS (MC18). As the amount of GGBFS content increases the chemically combined water increases. The x-ray diffraction (XRD) proved that as the amount of CoW content increases, the degree of crystallinity increases. Conversely, the replacement of AACW by GGBFS leads to increase the amorphiticity character. The infrared spectroscopy (FTIR) confirms the higher reactivity of GGBFS compared to CoW as a result of successive hydration products formation, enhancing the compaction of microstructure as observed in scanning electron microscopy (SEM).
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来源期刊
Advances in Materials Research-An International Journal
Advances in Materials Research-An International Journal MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
3.50
自引率
27.30%
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