Ni-GDC和Ni-YSZ电极在固体氧化物电解和燃料电池模式下工作

IF 1.2 4区工程技术 Q3 THERMODYNAMICS

Journal of Thermal Science and Technology Pub Date : 2021-01-01 DOI:10.1299/jtst.2021jtst0013

A. Sciazko, Takaaki Shimura, Y. Komatsu, N. Shikazono

{"title":"Ni-GDC和Ni-YSZ电极在固体氧化物电解和燃料电池模式下工作","authors":"A. Sciazko, Takaaki Shimura, Y. Komatsu, N. Shikazono","doi":"10.1299/jtst.2021jtst0013","DOIUrl":null,"url":null,"abstract":"In the present study, solid oxide cells (SOCs) were operated in the electricity generation (solid oxide fuel cell, SOFC) mode and the hydrogen production (solid oxide electrolysis cell, SOEC) mode. The fuel electrodes fabricated with nickel-gadolinia doped ceria (Ni-GDC) and nickel-yttria stabilized zirconia (Ni-YSZ) composites were investigated. The correlations between changes in the microstructure and degradation of electrochemical performance are discussed. The degradation mechanisms correlated with Ni phase were found to be similar for Ni-GDC and Ni-YSZ electrodes. On the other hand, the stability of the ceramic phase differs significantly between the two electrode materials.","PeriodicalId":17405,"journal":{"name":"Journal of Thermal Science and Technology","volume":null,"pages":null},"PeriodicalIF":1.2000,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"29","resultStr":"{\"title\":\"Ni-GDC and Ni-YSZ electrodes operated in solid oxide electrolysis and fuel cell modes\",\"authors\":\"A. Sciazko, Takaaki Shimura, Y. Komatsu, N. Shikazono\",\"doi\":\"10.1299/jtst.2021jtst0013\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In the present study, solid oxide cells (SOCs) were operated in the electricity generation (solid oxide fuel cell, SOFC) mode and the hydrogen production (solid oxide electrolysis cell, SOEC) mode. The fuel electrodes fabricated with nickel-gadolinia doped ceria (Ni-GDC) and nickel-yttria stabilized zirconia (Ni-YSZ) composites were investigated. The correlations between changes in the microstructure and degradation of electrochemical performance are discussed. The degradation mechanisms correlated with Ni phase were found to be similar for Ni-GDC and Ni-YSZ electrodes. On the other hand, the stability of the ceramic phase differs significantly between the two electrode materials.\",\"PeriodicalId\":17405,\"journal\":{\"name\":\"Journal of Thermal Science and Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.2000,\"publicationDate\":\"2021-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"29\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Thermal Science and Technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1299/jtst.2021jtst0013\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"THERMODYNAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Thermal Science and Technology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1299/jtst.2021jtst0013","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"THERMODYNAMICS","Score":null,"Total":0}

引用次数: 29

摘要

在本研究中，固体氧化物电池(soc)在发电(固体氧化物燃料电池，SOFC)模式和制氢(固体氧化物电解电池，SOEC)模式下运行。研究了用掺镍钆氧化铈(Ni-GDC)和镍钇稳定氧化锆(Ni-YSZ)复合材料制备燃料电极。讨论了微观结构变化与电化学性能退化之间的关系。Ni- gdc电极和Ni- ysz电极的Ni相降解机制相似。另一方面，陶瓷相的稳定性在两种电极材料之间存在显著差异。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Ni-GDC and Ni-YSZ electrodes operated in solid oxide electrolysis and fuel cell modes

In the present study, solid oxide cells (SOCs) were operated in the electricity generation (solid oxide fuel cell, SOFC) mode and the hydrogen production (solid oxide electrolysis cell, SOEC) mode. The fuel electrodes fabricated with nickel-gadolinia doped ceria (Ni-GDC) and nickel-yttria stabilized zirconia (Ni-YSZ) composites were investigated. The correlations between changes in the microstructure and degradation of electrochemical performance are discussed. The degradation mechanisms correlated with Ni phase were found to be similar for Ni-GDC and Ni-YSZ electrodes. On the other hand, the stability of the ceramic phase differs significantly between the two electrode materials.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of Thermal Science and Technology 物理-热力学

CiteScore

2.30

自引率

8.30%

发文量

审稿时长

5 months

期刊介绍： JTST covers a variety of fields in thermal engineering including heat and mass transfer, thermodynamics, combustion, bio-heat transfer, micro- and macro-scale transport phenomena and practical thermal problems in industrial applications.