微孔铜(II)二羧酸酯(富马酸酯、对苯二甲酸酯和反式-1,4-环己二羧酸酯)的气体吸附表征

IF 1.4 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Chemistry Letters Pub Date : 2001-02-01 DOI:10.1246/CL.2001.122

K. Seki, S. Takamizawa, W. Mori

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引用次数: 71

摘要

以铜盐和二羧酸为原料合成了一些微孔配位聚合物。用气体吸附法对这些结构进行了表征。测试了这些配位聚合物在高压下的甲烷吸附能力。测定结果表明，这些配位聚合物具有均匀的微孔，甲烷吸附能力与沸石5A基本相同。

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Characterization of Microporous Copper(II) Dicarboxylates (Fumarate, Terephthalate, and trans-1,4-Cyclohexanedicarboxylate) by Gas Adsorption

Some microporous coordination polymers have been synthesized from copper salts and dicarboxylic acids. These stuctures were characterized by gas adsorption methods. The methane adsorption capacities of these coordination polymers were measured under high pressure. The measurement disclosed that these coordination polymers had uniform micropores and methane adsorption capacities almost the same as that of zeolite 5A.

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来源期刊

Chemistry Letters 化学-化学综合

CiteScore

3.00

自引率

6.20%

发文量

260

审稿时长

1.2 months

期刊介绍： Chemistry Letters covers the following topics: -Organic Chemistry- Physical Chemistry- Inorganic Chemistry- Analytical Chemistry- Materials Chemistry- Polymer Chemistry- Supramolecular Chemistry- Organometallic Chemistry- Coordination Chemistry- Biomolecular Chemistry- Natural Products and Medicinal Chemistry- Electrochemistry