太阳系前钻石中的惰性气体II:组分丰度反映热处理过程

G. Huss, R. Lewis
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引用次数: 152

摘要

-利用Huss和Lewis, 1994a(论文I)中导出的同位素组成,测定了8类原始球粒陨石中15个钻石分离物中P3、HL和P6稀有气体组分的丰度。在一个陨石类别中,这些成分的相对丰度与宿主陨石的岩石学亚型相关,表明变质作用是导致这些变化的主要原因。金刚石样品中P3、HL和P6的相对丰度可以通过热处理单一的金刚石混合物来理解,就像现在在CI和CM2球粒陨石中发现的那样。在相对温和的加热下,原始钻石首先会失去低温P3气体和“不稳定”的HL成分。与这些成分的释放相关的质量损失使剩余金刚石的HL和P6含量相对于未加工的金刚石增加。较高的温度会破坏主要的HL载体,而幸存钻石的HL含量基本保持不变。同时,P6载流子开始优先失去轻惰性气体。经历过变质温度≥650℃的陨石,通过与周围矿物的化学反应,基本上失去了所有的太阳系前钻石。P3丰度似乎只与钻石所经历的最高温度有关,因此与周围环境的性质无关。如果所有类别都继承了相同的原始钻石混合物,那么P3丰度将把不同陨石类别的变质鳞片联系在一起。然而,如果P3丰度显示的温度高于适用于宿主陨石的其他温度计,那么P3丰度可能包含有关吸积之前加热的信息。变质程度最低的EH、CV和CO球粒陨石中的钻石似乎带有增生前热处理的记录。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Noble gases in presolar diamonds II: Component abundances reflect thermal processing
— Using the isotopic compositions derived in Huss and Lewis, 1994a (Paper I), abundances of the P3, HL, and P6 noble-gas components were determined for 15 diamond separates from primitive chondrites of 8 chondrite classes. Within a meteorite class, the relative abundances of these components correlate with the petrologic subtype of the host meteorite, indicating that metamorphism is primarily responsible for the variations. Relative abundances of P3, HL, and P6 among diamond samples can be understood in terms of thermal processing of a single mixture of diamonds like those now found in CI and CM2 chondrites. With relatively gentle heating, primitive diamonds first lose their low-temperature P3 gases and a “labile” fraction of the HL component. Mass loss associated with release of these components produces an increase in the HL and P6 content of the remaining diamond relative to unprocessed diamond. Higher temperatures initiate destruction of the main HL carrier, while the HL content of the surviving diamonds remains essentially constant. At the same time, the P6 carrier begins to preferentially lose light noble gases. Meteorites that have experienced metamorphic temperatures ≳650 °C have lost essentially all of their presolar diamond through chemical reactions with surrounding minerals. The P3 abundance seems to be a function only of the maximum temperature experienced by the diamonds and thus is independent of the nature of the surrounding environment. If all classes inherited the same mixture of primitive diamonds, then P3 abundances would tie together the metamorphic scales in different meteorite classes. However, if the P3 abundance indicates a higher temperature than do other thermometers applicable to the host meteorite, then the P3 abundance may contain information about heating prior to accretion. Diamonds in the least metamorphosed EH, CV, and CO chondrites seem to carry a record of pre-accretionary thermal processing.
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