功能聚合物控制合成的现代趋势:基本方面和实际应用

IF 7 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Reviews Pub Date : 2021-01-01 DOI:10.1070/RCR4964

D. F. Grishin, I. Grishin

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引用次数: 7

摘要

本文对可控自由基聚合(CRP)或可逆失活自由基聚合(RDRP)的主要趋势进行了批判性分析，RDRP是合成具有特定参数和性能的明确定义的共聚物和共聚物的最有效方法。本文综述了三种典型的CRP反应的最新进展:氮氧化物介导聚合反应、可逆加成-断裂链转移聚合反应和原子转移自由基聚合反应。重点讨论了光引发和光催化在CRP中的应用前景。这种方法最近得到了深入的探索，它使聚合物化学的合成方法更接近于生物体内发生的光诱导大分子合成过程。给出了CRP技术在工业上的实际应用实例，以获得具有工业价值的高科技聚合物产品。参考书目包括429篇参考文献。

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Modern trends in controlled synthesis of functional polymers: fundamental aspects and practical applications

Major trends in controlled radical polymerization (CRP) or reversible-deactivation radical polymerization (RDRP), the most efficient method of synthesis of well-defined homo- and copolymers with specified parameters and properties, are critically analyzed. Recent advances associated with the three classical versions of CRP: nitroxide mediated polymerization, reversible addition-fragmentation chain transfer polymerization and atom transfer radical polymerization, are considered. Particular attention is paid to the prospects for the application of photoinitiation and photocatalysis in CRP. This approach, which has been intensively explored recently, brings synthetic methods of polymer chemistry closer to the light-induced processes of macromolecular synthesis occurring in living organisms. Examples are given of practical application of CRP techniques to obtain industrially valuable, high-tech polymeric products. The bibliography includes 429 references.

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来源期刊

Russian Chemical Reviews 化学-化学综合

CiteScore

13.00

自引率

5.20%

发文量

审稿时长

6-12 weeks

期刊介绍： Russian Chemical Reviews serves as a complete translation of the esteemed monthly review journal Uspekhi Khimii, which has been a prominent figure in Russian scientific journals since its establishment in 1932. It offers comprehensive access to the advancements made by chemists from Russia and other former Soviet Union countries. Established in 1932, Russian Chemical Reviews is committed to publishing timely and significant review articles encompassing various facets of modern chemistry, including chemical physics, physical chemistry, computational and theoretical chemistry, catalysis, coordination chemistry, analytical chemistry, organic, organometallic, and organoelement chemistry, chemistry of macromolecules, applied chemistry, biochemistry, bio-organic chemistry, biomolecular chemistry, medicinal chemistry, materials chemistry, nanochemistry, nanostructures, and environmental chemistry.