沸点与德拜温度之间的统计相互关系

E. Grycko
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引用次数: 0

摘要

德拜温度Θ物质的D在固态理论中起作用;然而,它的实验测定需要一个复杂的装置,使得Θ D的值无法用于许多物质。对于沸点和分子质量已知的物质,提出了近似Θ D的统计可能性。这种近似是基于零熵温度的概念,它作为一个回归量;统计上的考虑表明回归量和德拜温度之间有很强的相关性。这一结果可以解释为流体和固体理论之间的桥梁。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
On a Statistical Interrelation Between Boiling Point and Debye Temperature
Debye temperature Θ D of a substance plays a role in Solid State Theory; its experimental determination however requires a sophisticated device such that the value of Θ D is not available for many substances. A statistical possibility of approximation of Θ D is presented for substances whose boiling point and molecular mass are known. This approximation is based on the notion of zero entropy temperature, which serves as a regressor; statistical considerations reveal a strong correlation between the regressor and Debye temperature. This result can be interpreted as a bridge between Fluid and Solid State Theories.
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来源期刊
Transport Theory and Statistical Physics
Transport Theory and Statistical Physics 物理-物理:数学物理
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