从合成到生物大分子的聚合物动力学

IF 0.5 Q4 MATHEMATICS, INTERDISCIPLINARY APPLICATIONS
Complex Systems Pub Date : 2008-02-27 DOI:10.1063/1.2897833
D. Richter, K. Niedźwiedź, M. Monkenbusch, A. Wischnewski, R. Biehl, B. Hoffmann, R. Merkel
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引用次数: 0

摘要

高分辨率中子散射加上对对比条件的细致选择,使包括生物分子在内的软材料在空间和时间上的大规模动力学得以实现。在这篇文章中,我们提出了两个例子。一个来自合成聚合物领域,另一个来自生物分子领域。首先,我们将讨论具有非常不同组分玻璃化转变温度的混相聚合物共混物的特殊动力学。聚甲基丙烯酸甲酯(PMMA)和聚环氧乙烷(PEO)是完全可混溶的,但玻璃化转变温度相差200 K。我们在五个数量级的时间框架内,对从埃到纳米范围内的快分量的动力学进行了准弹性中子散射研究。所有数据可以一致地用随机摩擦的Rouse模型来描述,反映了几乎冻结的PMMA矩阵对快速移动PEO施加的随机环境。在第二部分,我们将涉及一些新的发展……
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Polymer Dynamics from Synthetic to Biological Macromolecules
High resolution neutron scattering together with a meticulous choice of the contrast conditions allows to access the large scale dynamics of soft materials including biological molecules in space and time. In this contribution we present two examples. One from the world of synthetic polymers, the other from biomolecules. First, we will address the peculiar dynamics of miscible polymer blends with very different component glass transition temperatures. Polymethylmetacrylate (PMMA), polyethyleneoxide (PEO) are perfectly miscible but exhibit a difference in the glass transition temperature by 200 K. We present quasielastic neutron scattering investigations on the dynamics of the fast component in the range from angstroms to nanometers over a time frame of five orders of magnitude. All data may be consistently described in terms of a Rouse model with random friction, reflecting the random environment imposed by the nearly frozen PMMA matrix on the fast mobile PEO. In the second part we touch on some new devel...
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来源期刊
Complex Systems
Complex Systems MATHEMATICS, INTERDISCIPLINARY APPLICATIONS-
CiteScore
1.80
自引率
25.00%
发文量
18
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