第四系高密度聚乙烯(HDPE)复合材料的耐候性:焊缝、配方和降解对拉伸性能的影响

IF 2.702 Q1 Materials Science
David Viljoen, Johan Labuschagné, Ines Kuehnert
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引用次数: 0

摘要

本文研究了焊接线、添加剂和QUV老化程度对含碳酸钙、稳定剂和炭黑/SEBS母粒的高密度聚乙烯复合材料拉伸性能的影响。利用ftir衍生的羰基、双键和碳酸盐指标进行曲线拟合,表征风化程度,以便对含碳酸钙和不含碳酸钙的试样进行比较。焊缝试样的退化速度比参考试样快,而试样的暴露表面的退化速度比未暴露的表面快。ISO G154循环1和循环6风化协议的比较。发现添加剂在降低氧化降解方面是有效的,尽管在高负荷和混合系统中效果会降低。这些发现反映在试样的力学性能上,随着时效的增加,改性试样甚至表现出广泛改善的性能。断裂伸长率对风化作用最为敏感,几乎所有试件的断裂伸长率随风化作用的增加而退化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

The weathering resistance of quaternary High-density polyethylene (HDPE) composites: Effects of weld lines, formulation and degradation on tensile properties

The weathering resistance of quaternary High-density polyethylene (HDPE) composites: Effects of weld lines, formulation and degradation on tensile properties

In this work, the effects of weld lines, additives and the degree of QUV weathering on the tensile behavior of a range of high-density polyethylene composites with calcium carbonate, stabilizers and a carbon black/SEBS masterbatch are studied. The degree of weathering is characterized using FTIR-derived carbonyl, double-bond and carbonate indexes based on curve fitting, to allow for the fairer comparison of specimens with and without calcium carbonate. Weld-line specimens exhibited more rapid degradation than that seen in the reference specimens, while the exposed surfaces of the specimens degraded more quickly than the unexposed surfaces. ISO G154 Cycle 1 and Cycle 6 weathering protocols were compared. The additives were found to be effective at decreasing oxidative degradation, albeit with reduced effects at higher loadings and in mixed systems. These findings were mirrored in the mechanical properties of the specimens, with the modified specimens even exhibiting broadly improved properties with increasing aging. Elongation at break was most sensitive to weathering, with increasing degradation with increasing weathering across almost all specimens.

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来源期刊
CiteScore
5.20
自引率
0.00%
发文量
0
审稿时长
1.8 months
期刊介绍: Part A: Polymer Chemistry is devoted to studies in fundamental organic polymer chemistry and physical organic chemistry. This includes all related topics (such as organic, bioorganic, bioinorganic and biological chemistry of monomers, polymers, oligomers and model compounds, inorganic and organometallic chemistry for catalysts, mechanistic studies, supramolecular chemistry aspects relevant to polymer...
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