{"title":"标准正态化学反应和化学松弛。第3部分。-不同热力学条件下溶液中的反应","authors":"H. Hayman","doi":"10.1039/TF9716703240","DOIUrl":null,"url":null,"abstract":"The method described previously 2 for obtaining the relaxation times, normal coordinates and normal modes of relaxation of a non-ideal chemical system at constant temperature and pressure is extended to relaxation under adiabatic conditions and/or at constant volume; in each case the normal modes of relaxation are obtained as an orthonormal set satisfying orthonormality conditions similar to those pertaining to constant temperature and pressure. First-order perturbation theory is used for evaluating the various corrections required when the simple dilute-solution theory 1 is used at concentrations which are too high for the theory to be strictly applicable.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"3240-3246"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716703240","citationCount":"4","resultStr":"{\"title\":\"Orthonormal chemical reactions and chemical relaxation. Part 3.—Reactions in solution under various thermodynamic conditions\",\"authors\":\"H. Hayman\",\"doi\":\"10.1039/TF9716703240\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The method described previously 2 for obtaining the relaxation times, normal coordinates and normal modes of relaxation of a non-ideal chemical system at constant temperature and pressure is extended to relaxation under adiabatic conditions and/or at constant volume; in each case the normal modes of relaxation are obtained as an orthonormal set satisfying orthonormality conditions similar to those pertaining to constant temperature and pressure. First-order perturbation theory is used for evaluating the various corrections required when the simple dilute-solution theory 1 is used at concentrations which are too high for the theory to be strictly applicable.\",\"PeriodicalId\":23290,\"journal\":{\"name\":\"Transactions of The Faraday Society\",\"volume\":\"67 1\",\"pages\":\"3240-3246\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1039/TF9716703240\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/TF9716703240\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716703240","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Orthonormal chemical reactions and chemical relaxation. Part 3.—Reactions in solution under various thermodynamic conditions
The method described previously 2 for obtaining the relaxation times, normal coordinates and normal modes of relaxation of a non-ideal chemical system at constant temperature and pressure is extended to relaxation under adiabatic conditions and/or at constant volume; in each case the normal modes of relaxation are obtained as an orthonormal set satisfying orthonormality conditions similar to those pertaining to constant temperature and pressure. First-order perturbation theory is used for evaluating the various corrections required when the simple dilute-solution theory 1 is used at concentrations which are too high for the theory to be strictly applicable.
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