极性气体的平衡性质。第2部分。-某些极性气体的二次介电维利系数

Transactions of The Faraday Society Pub Date : 1971-01-01 DOI:10.1039/TF9716702915

A. N. Barnes, L. E. Sutton

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引用次数: 6

摘要

测定了5种极性气体CHF3、CHF2Cl、CH3Cl、CH2:CF2和(CH3)2O在30、50和70℃时的二次介电系数。对于CF3Cl和CF2Cl2气体，仅在50°C下测量。实验结果与极性气体分子间势的预测结果进行了比较。事实证明，这些方法都不完全令人满意。

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Equilibrium properties of polar gases. Part 2.—The second dielectric virial coefficients of some polar gases

The second dielectric virial coefficients ℬ for five polar gases CHF3, CHF2Cl, CH3Cl, CH2:CF2 and (CH3)2O were measured at 30, 50 and 70°C. for the gases CF3Cl and CF2Cl2, ℬ was measured at 50°C only. The experimental results were compared with those predicted by the forms of intermolecular potential that have been suggested for polar gases. None of these proves to be entirely satisfactory.

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Transactions of The Faraday Society

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