Hg(3P0)反应的相移研究。第2部分。- Hg(3P0)与水和醇的配合物

Transactions of The Faraday Society Pub Date : 1971-01-01 DOI:10.1039/TF9716702567

C. G. Freeman, M. McEwan, R. Claridge, L. F. Phillips

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引用次数: 8

摘要

测定了Hg(3P0)与H2O、D2O和一些醇的激发配合物的辐射寿命、解离能下限和双分子和三分子反应生成的速率常数。结果讨论了在R-OH分子与Hg(3P0)反应过程中可能发生的替代过程。

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Phase-shift studies of Hg(3P0) reactions. Part 2.—Complexes of Hg(3P0) with water and alcohols

Radiative lifetimes, lower limits for dissociation energies, and rate constants for formation by bimolecular and termolecular reactions, have been determined for the excited complexes of Hg(3P0) with H2O, D2O, and a number of alcohols. The results are discussed in terms of the alternative processes that can occur during reaction of an R—OH molecule with Hg(3P0).

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Transactions of The Faraday Society

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