{"title":"草酸在金上的阳极氧化","authors":"J. W. Johnson, S. Mueller, W. James","doi":"10.1039/TF9716702167","DOIUrl":null,"url":null,"abstract":"The anodic oxidation of oxalic acid on Au has been studied at 80°C in aqueous media. The reaction rate was measured as a function of potential, oxalic acid concentration, pH, and temperature in H2SO4+ K2SO4+ KOH solutions of unit ionic strength. The oxalic acid was oxidized in acidic media to CO2. A first-order dependence of the rate on both pH and undissociated oxalic acid was found. The first decarboxylation step appears to be rate determining.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"2167-2173"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716702167","citationCount":"20","resultStr":"{\"title\":\"Anodic oxidation of oxalic acid on gold\",\"authors\":\"J. W. Johnson, S. Mueller, W. James\",\"doi\":\"10.1039/TF9716702167\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The anodic oxidation of oxalic acid on Au has been studied at 80°C in aqueous media. The reaction rate was measured as a function of potential, oxalic acid concentration, pH, and temperature in H2SO4+ K2SO4+ KOH solutions of unit ionic strength. The oxalic acid was oxidized in acidic media to CO2. A first-order dependence of the rate on both pH and undissociated oxalic acid was found. The first decarboxylation step appears to be rate determining.\",\"PeriodicalId\":23290,\"journal\":{\"name\":\"Transactions of The Faraday Society\",\"volume\":\"67 1\",\"pages\":\"2167-2173\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1039/TF9716702167\",\"citationCount\":\"20\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/TF9716702167\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716702167","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The anodic oxidation of oxalic acid on Au has been studied at 80°C in aqueous media. The reaction rate was measured as a function of potential, oxalic acid concentration, pH, and temperature in H2SO4+ K2SO4+ KOH solutions of unit ionic strength. The oxalic acid was oxidized in acidic media to CO2. A first-order dependence of the rate on both pH and undissociated oxalic acid was found. The first decarboxylation step appears to be rate determining.
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