{"title":"SiBr的紫外光谱","authors":"G. Oldershaw, K. Robinson","doi":"10.1039/TF9716701870","DOIUrl":null,"url":null,"abstract":"The absorption spectrum of SiBr, observed in the flash photolysis of SiBr4, consists of the B2Σ—X2Π system and a number of new band systems at shorter wavelengths. One of these is shown to be analogous to the C2Π—X2Π systems of SiF and SiCl, and state C has the following parameters : Te= 41 051 cm–1, A= 12 cm–1, ωe= 531 cm–1, ωexe= 2 cm–1. Analyses of the remaining band systems are also discussed.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"1870-1874"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716701870","citationCount":"6","resultStr":"{\"title\":\"Ultra-violet spectrum of SiBr\",\"authors\":\"G. Oldershaw, K. Robinson\",\"doi\":\"10.1039/TF9716701870\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The absorption spectrum of SiBr, observed in the flash photolysis of SiBr4, consists of the B2Σ—X2Π system and a number of new band systems at shorter wavelengths. One of these is shown to be analogous to the C2Π—X2Π systems of SiF and SiCl, and state C has the following parameters : Te= 41 051 cm–1, A= 12 cm–1, ωe= 531 cm–1, ωexe= 2 cm–1. Analyses of the remaining band systems are also discussed.\",\"PeriodicalId\":23290,\"journal\":{\"name\":\"Transactions of The Faraday Society\",\"volume\":\"67 1\",\"pages\":\"1870-1874\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1039/TF9716701870\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/TF9716701870\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716701870","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The absorption spectrum of SiBr, observed in the flash photolysis of SiBr4, consists of the B2Σ—X2Π system and a number of new band systems at shorter wavelengths. One of these is shown to be analogous to the C2Π—X2Π systems of SiF and SiCl, and state C has the following parameters : Te= 41 051 cm–1, A= 12 cm–1, ωe= 531 cm–1, ωexe= 2 cm–1. Analyses of the remaining band systems are also discussed.
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