{"title":"N-Cl键的35Cl核四极共振","authors":"R. Hart, M. Whitehead","doi":"10.1039/TF9716701569","DOIUrl":null,"url":null,"abstract":"The 35Cl n.q.r. frequencies of seven N-chloro molecules are reported and with those of five additional molecules in the literature, interpreted using BEEM and BEEM-π. The frequency is dependent on the hybridization of the N atom: with tr1tr1tr1π2 hybridized N the 35Cl frequency is around 55 MHz, with tr1tr1tr2π1hybridized N around 46 MHz and with te1te1te1te2 hybridized N at 44 MHz.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"727 1","pages":"1569-1575"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716701569","citationCount":"11","resultStr":"{\"title\":\"35Cl nuclear quadrupole resonance of the N—Cl bond\",\"authors\":\"R. Hart, M. Whitehead\",\"doi\":\"10.1039/TF9716701569\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The 35Cl n.q.r. frequencies of seven N-chloro molecules are reported and with those of five additional molecules in the literature, interpreted using BEEM and BEEM-π. The frequency is dependent on the hybridization of the N atom: with tr1tr1tr1π2 hybridized N the 35Cl frequency is around 55 MHz, with tr1tr1tr2π1hybridized N around 46 MHz and with te1te1te1te2 hybridized N at 44 MHz.\",\"PeriodicalId\":23290,\"journal\":{\"name\":\"Transactions of The Faraday Society\",\"volume\":\"727 1\",\"pages\":\"1569-1575\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1039/TF9716701569\",\"citationCount\":\"11\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/TF9716701569\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716701569","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
35Cl nuclear quadrupole resonance of the N—Cl bond
The 35Cl n.q.r. frequencies of seven N-chloro molecules are reported and with those of five additional molecules in the literature, interpreted using BEEM and BEEM-π. The frequency is dependent on the hybridization of the N atom: with tr1tr1tr1π2 hybridized N the 35Cl frequency is around 55 MHz, with tr1tr1tr2π1hybridized N around 46 MHz and with te1te1te1te2 hybridized N at 44 MHz.
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