{"title":"辐射与光化学基本过程的电子自旋共振研究。第7部分。-羧酸在低温下的γ-辐射分解","authors":"P. Ayscough, J. Oversby","doi":"10.1039/TF9716701365","DOIUrl":null,"url":null,"abstract":"The γ-radiolysis of eleven carboxylic acids at cryogenic temperatures has been examined by e.s.r. and matrix isolation techniques. Radical-anions RĊOOH– were identified in all the acids examined except cyclopropane carboxylic acid, and their reactions studied. The main features of the radiolysis may be interpreted by means of a mechanism similar to that proposed earlier for acetic acid.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"1365-1375"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716701365","citationCount":"15","resultStr":"{\"title\":\"Electron spin resonance studies of fundamental processes in radiation- and photo-chemistry. Part 7.—The γ-radiolysis of carboxylic acids at cryogenic temperatures\",\"authors\":\"P. Ayscough, J. Oversby\",\"doi\":\"10.1039/TF9716701365\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The γ-radiolysis of eleven carboxylic acids at cryogenic temperatures has been examined by e.s.r. and matrix isolation techniques. Radical-anions RĊOOH– were identified in all the acids examined except cyclopropane carboxylic acid, and their reactions studied. The main features of the radiolysis may be interpreted by means of a mechanism similar to that proposed earlier for acetic acid.\",\"PeriodicalId\":23290,\"journal\":{\"name\":\"Transactions of The Faraday Society\",\"volume\":\"67 1\",\"pages\":\"1365-1375\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1039/TF9716701365\",\"citationCount\":\"15\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/TF9716701365\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716701365","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Electron spin resonance studies of fundamental processes in radiation- and photo-chemistry. Part 7.—The γ-radiolysis of carboxylic acids at cryogenic temperatures
The γ-radiolysis of eleven carboxylic acids at cryogenic temperatures has been examined by e.s.r. and matrix isolation techniques. Radical-anions RĊOOH– were identified in all the acids examined except cyclopropane carboxylic acid, and their reactions studied. The main features of the radiolysis may be interpreted by means of a mechanism similar to that proposed earlier for acetic acid.
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