{"title":"用介电加热弛豫技术研究溶液中的快速反应","authors":"K. J. Ivin, J. McGarvey, E. Simmons","doi":"10.1039/TF9716700097","DOIUrl":null,"url":null,"abstract":"A microwave-pulse temperature-jump relaxation technique is described. Temperature rises of about 0.5 K may be produced in non-polar solvent media in about 1 µs. Spectrophotometric detection is used to monitor the resulting chemical relaxation. A conductimetric detection system is also described and applied to the measurement of relaxation times in the millisecond range in an aqueous solution.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"97-103"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716700097","citationCount":"6","resultStr":"{\"title\":\"Study of fast reactions in solution using a dielectric-heating relaxation technique\",\"authors\":\"K. J. Ivin, J. McGarvey, E. Simmons\",\"doi\":\"10.1039/TF9716700097\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A microwave-pulse temperature-jump relaxation technique is described. Temperature rises of about 0.5 K may be produced in non-polar solvent media in about 1 µs. Spectrophotometric detection is used to monitor the resulting chemical relaxation. A conductimetric detection system is also described and applied to the measurement of relaxation times in the millisecond range in an aqueous solution.\",\"PeriodicalId\":23290,\"journal\":{\"name\":\"Transactions of The Faraday Society\",\"volume\":\"67 1\",\"pages\":\"97-103\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1039/TF9716700097\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/TF9716700097\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716700097","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Study of fast reactions in solution using a dielectric-heating relaxation technique
A microwave-pulse temperature-jump relaxation technique is described. Temperature rises of about 0.5 K may be produced in non-polar solvent media in about 1 µs. Spectrophotometric detection is used to monitor the resulting chemical relaxation. A conductimetric detection system is also described and applied to the measurement of relaxation times in the millisecond range in an aqueous solution.
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