{"title":"纳米多孔对苯二甲酸铜[MIL-53(Cu)]的合成及其甲烷吸附剂的研究","authors":"Mansoor Anbia, Sara Sheykhi","doi":"10.1016/S1003-9953(11)60419-2","DOIUrl":null,"url":null,"abstract":"<div><p>Copper (II) dicarboxylate, MIL-53, metal-organic framework synthesized hydrothermally has been used for the first time as an adsorbent for methane gas adsorption. Methane adsorption capacity of MIL-53(Cu) was increased to about 8.52 mmol·g<sup>−1</sup> at 298 K and 35 bar for methane storage. The adsorbent was characterized by X-ray diffraction (XRD), Brunauer-Emmet-Teller (BET) method, Fourier transform infrared (FT-IR), thermo gravimetric analysis (TGA) and scanning electron microscopy (SEM). The adsorption property of CH<sub>4</sub>, on MIL-53(Cu) was investigated by volumetric measurement. The enhancement of CH<sub>4</sub> adsorption capacity of MIL-53(Cu) is attributed to the increase of micropore volume of MIL-53(Cu).</p></div>","PeriodicalId":56116,"journal":{"name":"Journal of Natural Gas Chemistry","volume":"21 6","pages":"Pages 680-684"},"PeriodicalIF":0.0000,"publicationDate":"2012-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1003-9953(11)60419-2","citationCount":"20","resultStr":"{\"title\":\"Synthesis of nanoporous copper terephthalate [MIL-53(Cu)] as a novel methane-storage adsorbent\",\"authors\":\"Mansoor Anbia, Sara Sheykhi\",\"doi\":\"10.1016/S1003-9953(11)60419-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Copper (II) dicarboxylate, MIL-53, metal-organic framework synthesized hydrothermally has been used for the first time as an adsorbent for methane gas adsorption. Methane adsorption capacity of MIL-53(Cu) was increased to about 8.52 mmol·g<sup>−1</sup> at 298 K and 35 bar for methane storage. The adsorbent was characterized by X-ray diffraction (XRD), Brunauer-Emmet-Teller (BET) method, Fourier transform infrared (FT-IR), thermo gravimetric analysis (TGA) and scanning electron microscopy (SEM). The adsorption property of CH<sub>4</sub>, on MIL-53(Cu) was investigated by volumetric measurement. The enhancement of CH<sub>4</sub> adsorption capacity of MIL-53(Cu) is attributed to the increase of micropore volume of MIL-53(Cu).</p></div>\",\"PeriodicalId\":56116,\"journal\":{\"name\":\"Journal of Natural Gas Chemistry\",\"volume\":\"21 6\",\"pages\":\"Pages 680-684\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2012-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1003-9953(11)60419-2\",\"citationCount\":\"20\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Natural Gas Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1003995311604192\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Natural Gas Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1003995311604192","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis of nanoporous copper terephthalate [MIL-53(Cu)] as a novel methane-storage adsorbent
Copper (II) dicarboxylate, MIL-53, metal-organic framework synthesized hydrothermally has been used for the first time as an adsorbent for methane gas adsorption. Methane adsorption capacity of MIL-53(Cu) was increased to about 8.52 mmol·g−1 at 298 K and 35 bar for methane storage. The adsorbent was characterized by X-ray diffraction (XRD), Brunauer-Emmet-Teller (BET) method, Fourier transform infrared (FT-IR), thermo gravimetric analysis (TGA) and scanning electron microscopy (SEM). The adsorption property of CH4, on MIL-53(Cu) was investigated by volumetric measurement. The enhancement of CH4 adsorption capacity of MIL-53(Cu) is attributed to the increase of micropore volume of MIL-53(Cu).
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