易合成孔径可调铁掺杂有序介孔碳

Haodong Tang, Guojun Lan, Jian Zhong, Huazhang Liu, Ying Li
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引用次数: 5

摘要

多孔碳材料孔径的精确控制对于研究金属颗粒的约束效应具有重要意义,因为纳米尺度范围内的孔径大小将决定金属纳米颗粒的物理和化学性质。本文报道了一种以Fe-SBA-15为硬模板,硼酸为扩孔剂合成可调孔径铁掺杂有序介孔碳材料的新方法。孔径可在3-6 nm范围内以0.4 nm的步长进行精确调节。由于掺杂铁的催化作用,炭化温度可降至773 K。该方法适用于孔径可调的金属嵌套多孔碳材料的简易合成。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Easy synthesis of iron doped ordered mesoporous carbon with tunable pore sizes

Precise control of the pore sizes for porous carbon materials is of importance to study the confinement effect of metal particles because the pore size in nanosize range will decide the physical and chemical properties of the metal nanoparticles. In this paper, we report a new approach for the synthesis of iron doped ordered mesoporous carbon materials with adjustable pore size using Fe-SBA-15 as hard template and boric acid as the pore expanding reagent. The pore size can be precisely adjusted by a step of 0.4 nm in the range of 3–6 nm. The carbonization temperature can be lowered to 773 K due to the catalytic role of the doped iron. The present approach is suitable for facile synthesis of metal imbedded porous carbon materials with tunable pore sizes.

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来源期刊
Journal of Natural Gas Chemistry
Journal of Natural Gas Chemistry 化学-工程:化工
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