挂汞电极上二甲亚砜中电位扫描计时电流测定

Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-10-01 Epub Date: 2010-12-07 DOI:10.1016/S0022-0728(96)80007-6

Jerry L. Jones, Herbert A. Fritsche Jr.

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引用次数: 8

摘要

二甲亚砜的电分析研究已扩展到悬挂汞滴电极。采用电位扫描计时安培法，对工作电极进行恒电位控制。用randes - sevik方程研究了几种离子在该体系中的扩散控制。本文测量了所选退极化剂的半波电位和几种载流子电解质的极化极限。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Potential sweep chronoamperometry in dimethyl sulfoxide at the hanging mercury drop electrode

Electroanalytical studies in dimethyl sulfoxide have been extended to the hanging mercury drop electrode. Potential sweep chronoamperometry was utilized with potentiostatic control of the working electrode. Several ions have been examined for diffusion control in this system by means of the Randies-Sevčik equation. Halfwave potentials of selected depolarizers and polarization limits of several carrier electrolytes have been measured.

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来源期刊

Journal of Electroanalytical Chemistry (1959)

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