{"title":"基于多金属氧酸盐和金属有机框架的双功能催化剂解毒双(2-氯乙基)硫和有机磷试剂","authors":"Masoud Taheri","doi":"10.1007/s10563-021-09347-3","DOIUrl":null,"url":null,"abstract":"<p>The bis(2-chloroethyl) sulfide, commonly named sulfur mustard, as a vesicant agent and the tabun, sarin, soman, and venomous X as organophosphorus nerve agents are the most notorious, used, and threatening chemical warfare agents which contamination by them make serious health problems. The most efficient method for sulfur mustard detoxification is its selective oxidation to its corresponding sulfoxide, which is a nontoxic product. While for organophosphorus nerve agents, the best strategy is the hydrolysis of their P–X bond. Various mono-functional catalysts have been introducing regarding these methods. In other words, they are only able to selective oxidation of sulfur mustard or hydrolysis of organophosphorus nerve agents or their simulants. However, due to the unpredictable use of these chemical warfare agents, for human and environmental safety, there is a need for dual-functional catalysts capable of both the selective oxidation of sulfur mustard and hydrolysis of organophosphorus agents. In this regard, the reported dual-functional catalysts for oxidation of sulfur mustard and hydrolysis of organophosphorus agents, or their simulants, are reviewed here. These catalysts are mainly polyoxometalates and minorly metal-organic frameworks based catalysts.</p>","PeriodicalId":509,"journal":{"name":"Catalysis Surveys from Asia","volume":"26 1","pages":"1 - 15"},"PeriodicalIF":2.1000,"publicationDate":"2021-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Polyoxometalates and Metal–Organic Frameworks Based Dual-Functional Catalysts for Detoxification of Bis(2-Chloroethyl) Sulfide and Organophosphorus Agents\",\"authors\":\"Masoud Taheri\",\"doi\":\"10.1007/s10563-021-09347-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The bis(2-chloroethyl) sulfide, commonly named sulfur mustard, as a vesicant agent and the tabun, sarin, soman, and venomous X as organophosphorus nerve agents are the most notorious, used, and threatening chemical warfare agents which contamination by them make serious health problems. The most efficient method for sulfur mustard detoxification is its selective oxidation to its corresponding sulfoxide, which is a nontoxic product. While for organophosphorus nerve agents, the best strategy is the hydrolysis of their P–X bond. Various mono-functional catalysts have been introducing regarding these methods. In other words, they are only able to selective oxidation of sulfur mustard or hydrolysis of organophosphorus nerve agents or their simulants. However, due to the unpredictable use of these chemical warfare agents, for human and environmental safety, there is a need for dual-functional catalysts capable of both the selective oxidation of sulfur mustard and hydrolysis of organophosphorus agents. In this regard, the reported dual-functional catalysts for oxidation of sulfur mustard and hydrolysis of organophosphorus agents, or their simulants, are reviewed here. These catalysts are mainly polyoxometalates and minorly metal-organic frameworks based catalysts.</p>\",\"PeriodicalId\":509,\"journal\":{\"name\":\"Catalysis Surveys from Asia\",\"volume\":\"26 1\",\"pages\":\"1 - 15\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2021-09-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Surveys from Asia\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10563-021-09347-3\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Surveys from Asia","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10563-021-09347-3","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Polyoxometalates and Metal–Organic Frameworks Based Dual-Functional Catalysts for Detoxification of Bis(2-Chloroethyl) Sulfide and Organophosphorus Agents
The bis(2-chloroethyl) sulfide, commonly named sulfur mustard, as a vesicant agent and the tabun, sarin, soman, and venomous X as organophosphorus nerve agents are the most notorious, used, and threatening chemical warfare agents which contamination by them make serious health problems. The most efficient method for sulfur mustard detoxification is its selective oxidation to its corresponding sulfoxide, which is a nontoxic product. While for organophosphorus nerve agents, the best strategy is the hydrolysis of their P–X bond. Various mono-functional catalysts have been introducing regarding these methods. In other words, they are only able to selective oxidation of sulfur mustard or hydrolysis of organophosphorus nerve agents or their simulants. However, due to the unpredictable use of these chemical warfare agents, for human and environmental safety, there is a need for dual-functional catalysts capable of both the selective oxidation of sulfur mustard and hydrolysis of organophosphorus agents. In this regard, the reported dual-functional catalysts for oxidation of sulfur mustard and hydrolysis of organophosphorus agents, or their simulants, are reviewed here. These catalysts are mainly polyoxometalates and minorly metal-organic frameworks based catalysts.
期刊介绍:
Early dissemination of important findings from Asia which may lead to new concepts in catalyst design is the main aim of this journal. Rapid, invited, short reviews and perspectives from academia and industry will constitute the major part of Catalysis Surveys from Asia . Surveys of recent progress and activities in catalytic science and technology and related areas in Asia will be covered regularly as well. We would appreciate critical comments from colleagues throughout the world about articles in Catalysis Surveys from Asia . If requested and thought appropriate, the comments will be included in the journal. We will be very happy if this journal stimulates global communication between scientists and engineers in the world of catalysis.