辐照环己烷溶液中的能量转移

Radiation Physics and Chemistry (1977) Pub Date : 1985-01-01 DOI:10.1016/0146-5724(85)90201-8

L.H. Luthjens, H.C. de Leng, L. Wojna´rovits, A. Hummel

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引用次数: 12

摘要

从电子清除剂CO2对环己烷溶剂荧光激发态产率的降低来看，离子复合生成该激发态的效率为0.4±0.1。使用顺式十氢化萘作为溶质的能量转移研究似乎为在产率为0.8 (100 eV)-1的辐照环己烷中形成更高激发态提供了证据。这些态能够快速地向溶质转移能量。

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Energy transfer in irradiated cyclohexane solutions

From the decrease of yield of solvent fluorescent excited states in cyclohexane by the electron scavenger CO₂ the efficiency of formation of this excited state from ion recombination is found to be 0.4 ± 0.1. Energy transfer studies using cis-decalin as a solute seem to provide evidence for the formation of higher excited states in irradiated cyclohexane with a yield of 0.8 (100 eV)^-1. These states are capable of fast energy transfer to the solute.

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来源期刊

Radiation Physics and Chemistry (1977)

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