{"title":"胶体氧化铁中和反应的增强","authors":"Akos Vertes","doi":"10.1016/0146-5724(85)90101-3","DOIUrl":null,"url":null,"abstract":"<div><p>Neutralization reaction was investigated in negative ferric hydrous oxide sols. The adsorption isotherm of OH<sup>-</sup> ions on the surface of colloidal particles was measured to provide the variation of their charge with pH. Impulse radiolysis generated the reacting ions in the sol. Using a fast DC conductivity setup for detection, a significant increase in the neutralization rate coefficient was found at low OH<sup>-</sup> concentrations. The phenomenon was discussed in terms of the theory of diffusion controlled reactions for particles interacting with Coulomb and Yukawa potential.</p></div>","PeriodicalId":101054,"journal":{"name":"Radiation Physics and Chemistry (1977)","volume":"26 6","pages":"Pages 641-645"},"PeriodicalIF":0.0000,"publicationDate":"1985-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0146-5724(85)90101-3","citationCount":"0","resultStr":"{\"title\":\"Enhancement of neutralization reaction in colloidal ferric hydrous oxide\",\"authors\":\"Akos Vertes\",\"doi\":\"10.1016/0146-5724(85)90101-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Neutralization reaction was investigated in negative ferric hydrous oxide sols. The adsorption isotherm of OH<sup>-</sup> ions on the surface of colloidal particles was measured to provide the variation of their charge with pH. Impulse radiolysis generated the reacting ions in the sol. Using a fast DC conductivity setup for detection, a significant increase in the neutralization rate coefficient was found at low OH<sup>-</sup> concentrations. The phenomenon was discussed in terms of the theory of diffusion controlled reactions for particles interacting with Coulomb and Yukawa potential.</p></div>\",\"PeriodicalId\":101054,\"journal\":{\"name\":\"Radiation Physics and Chemistry (1977)\",\"volume\":\"26 6\",\"pages\":\"Pages 641-645\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0146-5724(85)90101-3\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Radiation Physics and Chemistry (1977)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0146572485901013\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiation Physics and Chemistry (1977)","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0146572485901013","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Enhancement of neutralization reaction in colloidal ferric hydrous oxide
Neutralization reaction was investigated in negative ferric hydrous oxide sols. The adsorption isotherm of OH- ions on the surface of colloidal particles was measured to provide the variation of their charge with pH. Impulse radiolysis generated the reacting ions in the sol. Using a fast DC conductivity setup for detection, a significant increase in the neutralization rate coefficient was found at low OH- concentrations. The phenomenon was discussed in terms of the theory of diffusion controlled reactions for particles interacting with Coulomb and Yukawa potential.
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