间歇式脉动流和搅拌槽反应器中的化学反应

X. Ni, M.R. Mackley
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引用次数: 44

摘要

我们报告了使用间歇式脉动流反应器的实验观察结果。以氢氧化钠与乙酸乙酯的不可逆反应NaOH+CH3COOC2H5→CH3COONa+C2H5OH为例,在脉动流和搅拌槽反应器中进行了模拟。反应物质与羧甲基纤维素钠盐预混,以增加溶液的粘度,并使容器内的流体混合成为一个关键参数。结果表明,两种装置的反应动力学相似,带气问题仅限于搅拌槽式反应器。功率密度分析表明,脉动流反应器比搅拌槽反应器更节能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Chemical reaction in batch pulsatile flow and stirred tank reactors

We report experimental observations on the use of a batch pulsatile flow reactor. The irreversible reaction between sodium hydroxide and ethyl acetate, NaOH+CH3COOC2H5→CH3COONa+C2H5OH, is followed as a model example in both a pulsatile flow and a stirred tank reactor. Reaction species were premixed with carboxymethylcellulose sodium salt in order to increase the viscosity of the solution and to make the fluid mixing within the vessel a critical parameter. The results show that the reaction kinetics are similar for the two devices and air entrainment problems are limited to the stirred tank reactor. Power density considerations show that the pulsatile flow reactor is more energy efficient than the stirred tank reactor.

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