线性电压变化下伏安法自抑制现象的研究

Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-11-01 DOI:10.1016/0022-0728(66)80129-8

Etienne Laviron

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引用次数: 9

摘要

用线性扫描伏安法研究了不溶性物质可逆沉积形成抑制膜的自抑制现象。计算了CD12/n12v12νXXXm各参数值的理论曲线i = f(E)，所得结果可以计算出电流和电位峰随浓度或扫描速率的变化。所提出的理论解释了当氯化物在汞电极上发生阳极反应时所得到的示波极谱图的主要特征。

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Etude de phenomenes d'autoinhibition en voltammetrie a variation lineaire de tension

A study of autoinhibition phenomena in linear sweep voltammetry has been made for the case where the inhibiting film is formed by the reversible deposition of an insoluble material. The theoretical curves i = f(E) have been calculated for various values of the parameter CD $12$ /n $12$ v $12$ νXXX_m, the results obtained enable the variation of the current and the potential peak to be calculated as a function of the concentration or the rate of scanning.

The theory propounded explains the principal characteristics of the oscillopolarograms obtained when chlorides react anodically on the mercury electrode.

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Journal of Electroanalytical Chemistry (1959)

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