{"title":"γ-谷氨酸乙基解离的热力学研究","authors":"J. Llopis, A. Vallin","doi":"10.1016/0022-0728(66)80122-5","DOIUrl":null,"url":null,"abstract":"<div><p>The ionization constants of γ-ethyl glutamate have been determined, from 5–50° from e.m.f. measurements of cells without liquid junctions. The equations for ionization constants as a function of temperature are as follows : <figure><img></figure></p><p>Values for the derived thermodynamic quantities have been calculated. The results were interpreted in relation to those known for glutamic acid and α-amino-esters.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"12 5","pages":"Pages 422-435"},"PeriodicalIF":0.0000,"publicationDate":"1966-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80122-5","citationCount":"0","resultStr":"{\"title\":\"Etude thermodynamique de la dissociation du γ-glutamate d'ethyle\",\"authors\":\"J. Llopis, A. Vallin\",\"doi\":\"10.1016/0022-0728(66)80122-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The ionization constants of γ-ethyl glutamate have been determined, from 5–50° from e.m.f. measurements of cells without liquid junctions. The equations for ionization constants as a function of temperature are as follows : <figure><img></figure></p><p>Values for the derived thermodynamic quantities have been calculated. The results were interpreted in relation to those known for glutamic acid and α-amino-esters.</p></div>\",\"PeriodicalId\":100778,\"journal\":{\"name\":\"Journal of Electroanalytical Chemistry (1959)\",\"volume\":\"12 5\",\"pages\":\"Pages 422-435\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-0728(66)80122-5\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Electroanalytical Chemistry (1959)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0022072866801225\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electroanalytical Chemistry (1959)","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022072866801225","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Etude thermodynamique de la dissociation du γ-glutamate d'ethyle
The ionization constants of γ-ethyl glutamate have been determined, from 5–50° from e.m.f. measurements of cells without liquid junctions. The equations for ionization constants as a function of temperature are as follows :
Values for the derived thermodynamic quantities have been calculated. The results were interpreted in relation to those known for glutamic acid and α-amino-esters.
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