{"title":"找出一个天王星的线索","authors":"J. Flemming, H. Berg","doi":"10.1016/0022-0728(66)80118-3","DOIUrl":null,"url":null,"abstract":"<div><p>From the comparison of the <em>i</em>-<em>t</em> curves, obtained with thin-walled pointed capillaries, with the equations of koutecky and matsuda it is found that :</p><p>1. The majority of the first <em>i</em>-<em>t</em> curve is represented by Koutecky's equation.</p><p>2. Screening is not important for the deviations at the beginning of the drop life.</p><p>3. An improved agreement between experiment and theory can be obtained with a time-dependent correction term + (<em>b</em> +[39—<em>b</em>]<em>t</em>/τ) (following the idea of <span>Hans</span>) in the Koutecky equation.</p><p>4. The remaining deviation at the beginning of the drop-life (up to about 0.2 sec) can perhaps be given a physical meaning with a new equation.</p><p>5. The thin-walled pointed capillary can reduce but not eliminate the depletion effect.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"12 5","pages":"Pages 391-396"},"PeriodicalIF":0.0000,"publicationDate":"1966-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80118-3","citationCount":"1","resultStr":"{\"title\":\"Zum problem der idealen quecksilbertropfelektrode\",\"authors\":\"J. Flemming, H. Berg\",\"doi\":\"10.1016/0022-0728(66)80118-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>From the comparison of the <em>i</em>-<em>t</em> curves, obtained with thin-walled pointed capillaries, with the equations of koutecky and matsuda it is found that :</p><p>1. The majority of the first <em>i</em>-<em>t</em> curve is represented by Koutecky's equation.</p><p>2. Screening is not important for the deviations at the beginning of the drop life.</p><p>3. An improved agreement between experiment and theory can be obtained with a time-dependent correction term + (<em>b</em> +[39—<em>b</em>]<em>t</em>/τ) (following the idea of <span>Hans</span>) in the Koutecky equation.</p><p>4. The remaining deviation at the beginning of the drop-life (up to about 0.2 sec) can perhaps be given a physical meaning with a new equation.</p><p>5. The thin-walled pointed capillary can reduce but not eliminate the depletion effect.</p></div>\",\"PeriodicalId\":100778,\"journal\":{\"name\":\"Journal of Electroanalytical Chemistry (1959)\",\"volume\":\"12 5\",\"pages\":\"Pages 391-396\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-0728(66)80118-3\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Electroanalytical Chemistry (1959)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0022072866801183\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electroanalytical Chemistry (1959)","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022072866801183","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
From the comparison of the i-t curves, obtained with thin-walled pointed capillaries, with the equations of koutecky and matsuda it is found that :
1. The majority of the first i-t curve is represented by Koutecky's equation.
2. Screening is not important for the deviations at the beginning of the drop life.
3. An improved agreement between experiment and theory can be obtained with a time-dependent correction term + (b +[39—b]t/τ) (following the idea of Hans) in the Koutecky equation.
4. The remaining deviation at the beginning of the drop-life (up to about 0.2 sec) can perhaps be given a physical meaning with a new equation.
5. The thin-walled pointed capillary can reduce but not eliminate the depletion effect.
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