{"title":"化学动力学研究中的自动和库仑滴定","authors":"Peter W. Carr , Louis Meites","doi":"10.1016/0022-0728(66)80116-X","DOIUrl":null,"url":null,"abstract":"<div><p>The rate constants for the disproportionations of uranium(V) in perchlorate solutions having hydrogen-ion concentrations between 0.01 and 1.9 <em>M</em> have been evaluated by adding a solution of chromium(II) at a constant rate to one of uranium (VI), employing a vibrating dropping mercury electrode to follow the variation of the concentration of either uranium(VI) or uranium(V). The resulting values are in acceptable agreement with those obtained by other techniques.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"12 5","pages":"Pages 373-384"},"PeriodicalIF":0.0000,"publicationDate":"1966-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80116-X","citationCount":"11","resultStr":"{\"title\":\"Automatic and coulometric titrations in studies of chemical kinetics\",\"authors\":\"Peter W. Carr , Louis Meites\",\"doi\":\"10.1016/0022-0728(66)80116-X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The rate constants for the disproportionations of uranium(V) in perchlorate solutions having hydrogen-ion concentrations between 0.01 and 1.9 <em>M</em> have been evaluated by adding a solution of chromium(II) at a constant rate to one of uranium (VI), employing a vibrating dropping mercury electrode to follow the variation of the concentration of either uranium(VI) or uranium(V). The resulting values are in acceptable agreement with those obtained by other techniques.</p></div>\",\"PeriodicalId\":100778,\"journal\":{\"name\":\"Journal of Electroanalytical Chemistry (1959)\",\"volume\":\"12 5\",\"pages\":\"Pages 373-384\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-0728(66)80116-X\",\"citationCount\":\"11\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Electroanalytical Chemistry (1959)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/002207286680116X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electroanalytical Chemistry (1959)","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/002207286680116X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Automatic and coulometric titrations in studies of chemical kinetics
The rate constants for the disproportionations of uranium(V) in perchlorate solutions having hydrogen-ion concentrations between 0.01 and 1.9 M have been evaluated by adding a solution of chromium(II) at a constant rate to one of uranium (VI), employing a vibrating dropping mercury electrode to follow the variation of the concentration of either uranium(VI) or uranium(V). The resulting values are in acceptable agreement with those obtained by other techniques.
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