13CD3OH的HCN激光Stark光谱

G.R. Sudhakaran , M. Jackson , R.M. Lees , Li-Hong Xu , I. Mukhopadhyay
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引用次数: 2

摘要

利用HCN激光器的311 μm线研究了13CD3OH的激光斯塔克光谱。在vt = 1激发态的K = 2←3E1, q分支跃迁中,有大量的吸收谱线分布在J = 3 ~ 11个成员上。给出的所有指定跃迁的零场频率比从现有分子常数计算的频率精度更高。对于q分支级数,给出了分支原点和级数展开系数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Stark spectroscopy of 13CD3OH with the HCN laser

The laser Stark spectrum of 13CD3OH has been studied using the 311 μm line of the HCN laser. An extensive series of absorption lines has been observed and assigned to the J = 3 to 11 members of the K = 2 ← 3E1, Q-branch transition in the vt = 1 excited torsional state. Zero-field frequencies for all the assigned transitions are given with improved accuracy over those calculated from available molecular constants. For the Q-branch series, the branch origin and the series expansion coefficients are also presented.

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