I. Voicu , R. Alexandrescu , I. Morjan , M. Stoica , I. Ursu , V. Jianu
{"title":"均相气相CO2激光驱动反应红外合成SO3","authors":"I. Voicu , R. Alexandrescu , I. Morjan , M. Stoica , I. Ursu , V. Jianu","doi":"10.1016/0020-0891(92)90072-2","DOIUrl":null,"url":null,"abstract":"<div><p>By using a CO<sub>2</sub> laser operated at 10.6μm, a bimolecular reaction was induced in a binary SO<sub>2</sub>/O<sub>2</sub> gas mixture, with a sensitizer gas (SF<sub>6</sub>) as photo-absorbing species.</p><p>The infrared (IR) synthesis of SO<sub>3</sub> was performed in a flowing gas device equipped with a continuous trapping system of the reaction product. Vibrational energy transfer processes presumably should play a specific role in SO<sub>2</sub> excitation and reaction in the presence of SF<sub>6</sub>.</p></div>","PeriodicalId":81524,"journal":{"name":"Infrared physics","volume":"33 6","pages":"Pages 557-562"},"PeriodicalIF":0.0000,"publicationDate":"1992-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-0891(92)90072-2","citationCount":"1","resultStr":"{\"title\":\"Infrared synthesis of SO3 by homogeneous gas-phase CO2 laser-driven reactions\",\"authors\":\"I. Voicu , R. Alexandrescu , I. Morjan , M. Stoica , I. Ursu , V. Jianu\",\"doi\":\"10.1016/0020-0891(92)90072-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>By using a CO<sub>2</sub> laser operated at 10.6μm, a bimolecular reaction was induced in a binary SO<sub>2</sub>/O<sub>2</sub> gas mixture, with a sensitizer gas (SF<sub>6</sub>) as photo-absorbing species.</p><p>The infrared (IR) synthesis of SO<sub>3</sub> was performed in a flowing gas device equipped with a continuous trapping system of the reaction product. Vibrational energy transfer processes presumably should play a specific role in SO<sub>2</sub> excitation and reaction in the presence of SF<sub>6</sub>.</p></div>\",\"PeriodicalId\":81524,\"journal\":{\"name\":\"Infrared physics\",\"volume\":\"33 6\",\"pages\":\"Pages 557-562\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1992-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-0891(92)90072-2\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Infrared physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020089192900722\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Infrared physics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020089192900722","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Infrared synthesis of SO3 by homogeneous gas-phase CO2 laser-driven reactions
By using a CO2 laser operated at 10.6μm, a bimolecular reaction was induced in a binary SO2/O2 gas mixture, with a sensitizer gas (SF6) as photo-absorbing species.
The infrared (IR) synthesis of SO3 was performed in a flowing gas device equipped with a continuous trapping system of the reaction product. Vibrational energy transfer processes presumably should play a specific role in SO2 excitation and reaction in the presence of SF6.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
