碱催化甲醇硫代化过程中酸性气体转化为有机硫和氢的案例研究

IF 2.1 4区 化学 Q3 CHEMISTRY, PHYSICAL
Mohammad Reza Shabani, Mohammad Ali Moosavian, Sayed Javid Royaee, Yahya Zamani
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引用次数: 0

摘要

在碱/W/γ-Al2O3催化剂的催化下,以酸性气体代替纯H2S进行甲醇硫化反应。采用初湿浸渍法制备了催化剂,并用XRD、BET、NH3-TPD等方法对催化剂进行了表征。在固定床流动反应器中对浓度为12.2%mol的酸性气体进行了催化试验。H2S在常压下,360℃,H2S与甲醇的摩尔比为2,LHSV为0.5 h−1。然后将结果与使用纯H2S作为原料的情况进行了比较。由于催化剂参与烃类重整反应,在酸性气体进料中H2S转化率低于纯H2S进料。铯促进催化剂的效果最好。酸性气体中H2S转化率为92.8%。有机硫产物二甲基硫和甲硫醇的产率分别为87.3%和5.5%。反应器出口氢气量增加了约110%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Acid Gas Converting to Organosulfur and Hydrogen in Methanol Thiolation Using Alkali Promoted Catalysts: Case Study

An acid gas stream was utilized instead of pure H2S as feedstock in the methanol thiolation reaction with Alkali/W/γ-Al2O3 catalysts. The catalysts were synthesized through incipient wetness impregnation and characterized by XRD, BET, and NH3-TPD methods. The catalytic tests were performed in a fixed-bed flow reactor for an acid gas with 12.2%mol. H2S at atmospheric pressure, 360 °C, H2S to methanol molar ratio of 2, and LHSV of 0.5 h−1. The results were then compared with the case in which pure H2S was used as feedstock. H2S conversion was lower in the acid gas feed than in pure H2S feed due to participation of catalysts in hydrocarbon reforming reactions. Cesium-promoted catalysts gave the best results. H2S in acid gas was converted about 92.8%. The yields were reported about 87.3% and 5.5% for dimethyl sulfide and methanethiol as organosulfur products respectively. The amount of hydrogen increased by about 110% in the reactor outlet.

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来源期刊
Catalysis Surveys from Asia
Catalysis Surveys from Asia 化学-物理化学
CiteScore
4.80
自引率
0.00%
发文量
29
审稿时长
>12 weeks
期刊介绍: Early dissemination of important findings from Asia which may lead to new concepts in catalyst design is the main aim of this journal. Rapid, invited, short reviews and perspectives from academia and industry will constitute the major part of Catalysis Surveys from Asia . Surveys of recent progress and activities in catalytic science and technology and related areas in Asia will be covered regularly as well. We would appreciate critical comments from colleagues throughout the world about articles in Catalysis Surveys from Asia . If requested and thought appropriate, the comments will be included in the journal. We will be very happy if this journal stimulates global communication between scientists and engineers in the world of catalysis.
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