三氟化硼活化La-Faujasite沸石的合成及其作为异丁烷-异丁烯烷基化固体酸催化剂的应用

IF 0.125

Applied Petrochemical Research Pub Date : 2021-09-28 DOI:10.1007/s13203-021-00283-x

David Bolonio, Yolanda Sánchez-Palencia, María-Jesús García-Martínez, Marcelo F. Ortega, José Eugenio Ortiz, Jorge Costafreda, Laureano Canoira

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引用次数: 0

摘要

采用水热法合成了钠型Faujasite Y (Na-FAU)沸石，并与硫酸铵和氯化镧溶液进行交换，得到La-FAU催化剂。采用微晶x射线衍射、x射线荧光、比表面积、孔体积和Brönsted酸位对Na-FAU、NH4+-FAU和La-FAU三种分子筛进行了表征。用三氟化硼醚成功活化了La-FAU催化剂，并在异丁烷与异丁烯的烷基化反应中进行了长达112 h的测试，因为原始La-FAU催化剂表现出快速失活。

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La-Faujasite zeolite activated with boron trifluoride: synthesis and application as solid acid catalyst for isobutane–isobutene alkylation

The sodium form of Faujasite Y (Na-FAU) zeolite has been synthesized by the hydrothermal method, and it has been exchanged with ammonium sulphate and later with lanthanum (III) chloride solutions to obtain the La-FAU catalyst. The three zeolites Na-FAU, NH₄⁺-FAU and La-FAU have been characterized by microcrystalline X-ray diffraction, X-ray fluorescence, surface area, pore volume and Brönsted acid sites. The La-FAU catalyst has been successfully activated with boron trifluoride etherate, and it has been tested in the alkylation reaction of isobutane with isobutene up to 112 h of time on stream, since the raw La-FAU catalyst showed a rapid deactivation.

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来源期刊

Applied Petrochemical Research ENGINEERING, CHEMICAL-

自引率

0.00%

发文量

审稿时长

13 weeks

期刊介绍： Applied Petrochemical Research is a quarterly Open Access journal supported by King Abdulaziz City for Science and Technology and all the manuscripts are single-blind peer-reviewed for scientific quality and acceptance. The article-processing charge (APC) for all authors is covered by KACST. Publication of original applied research on all aspects of the petrochemical industry focusing on new and smart technologies that allow the production of value-added end products in a cost-effective way. Topics of interest include: • Review of Petrochemical Processes • Reaction Engineering • Design • Catalysis • Pilot Plant and Production Studies • Synthesis As Applied to any of the following aspects of Petrochemical Research: -Feedstock Petrochemicals: Ethylene Production, Propylene Production, Butylene Production, Aromatics Production (Benzene, Toluene, Xylene etc...), Oxygenate Production (Methanol, Ethanol, Propanol etc…), Paraffins and Waxes. -Petrochemical Refining Processes: Cracking (Steam Cracking, Hydrocracking, Fluid Catalytic Cracking), Reforming and Aromatisation, Isomerisation Processes, Dimerization and Polymerization, Aromatic Alkylation, Oxidation Processes, Hydrogenation and Dehydrogenation. -Products: Polymers and Plastics, Lubricants, Speciality and Fine Chemicals (Adhesives, Fragrances, Flavours etc...), Fibres, Pharmaceuticals.