Promising Binders of Complex Oligophenylenes Compounds with Metals for Creating Composites Based on Adaptive Hybrid-Structured Polymer Systems

The modern generation of instrumental composite materials with a fundamentally new mechanism of contact interaction with processed materials was created through the use of binder polymers with embedded metallocene fragments. The structure of hybrid oligomers obtained by the interaction of oligophenylene and complex compounds of vanadium, iron, and copper was determined; it is a combination of organic and inorganic fragments. Inorganic fragments are represented by metal ions and clusters, bonded by covalent and coordination bonds with organic fragments. Organic fragments have a metallocene structure connected by methylene sites with weakly conjugated benzene rings. Clusters and metal ions can be located both between the planes of metallocenes and weakly conjugated rings and between oligomer chains as their continuation.