Guolang Zhou , Linlin Chen , Xiaowei Li , Guiling Luo , Zhendong Yu , Jingzhou Yin , Lei Fan , Yanhong Chao , Lei Jiang , Wenshuai Zhu
{"title":"截断八面体LiMn2O4的构建用于从盐水中回收类电池电化学锂","authors":"Guolang Zhou , Linlin Chen , Xiaowei Li , Guiling Luo , Zhendong Yu , Jingzhou Yin , Lei Fan , Yanhong Chao , Lei Jiang , Wenshuai Zhu","doi":"10.1016/j.gee.2021.12.002","DOIUrl":null,"url":null,"abstract":"<div><p>The extraction of lithium from salt lakes or seawater has attracted worldwide attention because of the explosive growth of global demand for lithium products. The LiMn<sub>2</sub>O<sub>4</sub>-based electrochemical lithium recovery system is one of the strongest candidates for commercial application due to its high inserted capacity and low energy consumption. However, the surface orientation of LiMn<sub>2</sub>O<sub>4</sub> that facilitates Li diffusion happens to be prone to manganese dissolution making it a great challenge to obtain high lithium inserted capacity and long life simultaneously. Herein, we address this problem by designing a truncated octahedral LiMn<sub>2</sub>O<sub>4</sub> (Tr-oh LMO) in which the dominant (111) facets minimize Mn dissolution while a small portion of (100) facets facilitate the Li diffusion. Thus, this Tr-oh LMO-based electrochemical lithium recovery system shows excellent Li recovery performance with high inserted capacity (20.25 mg g<sup>−1</sup> per cycle) in simulated brine. In addition, the dissolution rate of manganese per 30 cycles is only 0.44% and the capacity maintained 85% of the initial after 30 cycles. These promising findings accelerate the practical application of LiMn<sub>2</sub>O<sub>4</sub> in electrochemical lithium recovery.</p></div>","PeriodicalId":12744,"journal":{"name":"Green Energy & Environment","volume":null,"pages":null},"PeriodicalIF":10.7000,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"14","resultStr":"{\"title\":\"Construction of truncated-octahedral LiMn2O4 for battery-like electrochemical lithium recovery from brine\",\"authors\":\"Guolang Zhou , Linlin Chen , Xiaowei Li , Guiling Luo , Zhendong Yu , Jingzhou Yin , Lei Fan , Yanhong Chao , Lei Jiang , Wenshuai Zhu\",\"doi\":\"10.1016/j.gee.2021.12.002\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The extraction of lithium from salt lakes or seawater has attracted worldwide attention because of the explosive growth of global demand for lithium products. The LiMn<sub>2</sub>O<sub>4</sub>-based electrochemical lithium recovery system is one of the strongest candidates for commercial application due to its high inserted capacity and low energy consumption. However, the surface orientation of LiMn<sub>2</sub>O<sub>4</sub> that facilitates Li diffusion happens to be prone to manganese dissolution making it a great challenge to obtain high lithium inserted capacity and long life simultaneously. Herein, we address this problem by designing a truncated octahedral LiMn<sub>2</sub>O<sub>4</sub> (Tr-oh LMO) in which the dominant (111) facets minimize Mn dissolution while a small portion of (100) facets facilitate the Li diffusion. Thus, this Tr-oh LMO-based electrochemical lithium recovery system shows excellent Li recovery performance with high inserted capacity (20.25 mg g<sup>−1</sup> per cycle) in simulated brine. In addition, the dissolution rate of manganese per 30 cycles is only 0.44% and the capacity maintained 85% of the initial after 30 cycles. These promising findings accelerate the practical application of LiMn<sub>2</sub>O<sub>4</sub> in electrochemical lithium recovery.</p></div>\",\"PeriodicalId\":12744,\"journal\":{\"name\":\"Green Energy & Environment\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":10.7000,\"publicationDate\":\"2023-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"14\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Green Energy & Environment\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2468025721002053\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Green Energy & Environment","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2468025721002053","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Construction of truncated-octahedral LiMn2O4 for battery-like electrochemical lithium recovery from brine
The extraction of lithium from salt lakes or seawater has attracted worldwide attention because of the explosive growth of global demand for lithium products. The LiMn2O4-based electrochemical lithium recovery system is one of the strongest candidates for commercial application due to its high inserted capacity and low energy consumption. However, the surface orientation of LiMn2O4 that facilitates Li diffusion happens to be prone to manganese dissolution making it a great challenge to obtain high lithium inserted capacity and long life simultaneously. Herein, we address this problem by designing a truncated octahedral LiMn2O4 (Tr-oh LMO) in which the dominant (111) facets minimize Mn dissolution while a small portion of (100) facets facilitate the Li diffusion. Thus, this Tr-oh LMO-based electrochemical lithium recovery system shows excellent Li recovery performance with high inserted capacity (20.25 mg g−1 per cycle) in simulated brine. In addition, the dissolution rate of manganese per 30 cycles is only 0.44% and the capacity maintained 85% of the initial after 30 cycles. These promising findings accelerate the practical application of LiMn2O4 in electrochemical lithium recovery.
期刊介绍:
Green Energy & Environment (GEE) is an internationally recognized journal that undergoes a rigorous peer-review process. It focuses on interdisciplinary research related to green energy and the environment, covering a wide range of topics including biofuel and bioenergy, energy storage and networks, catalysis for sustainable processes, and materials for energy and the environment. GEE has a broad scope and encourages the submission of original and innovative research in both fundamental and engineering fields. Additionally, GEE serves as a platform for discussions, summaries, reviews, and previews of the impact of green energy on the eco-environment.