封底图片:碳中和,第2卷,第4期,2023年7月

Zhihao Nie, Licheng Yu, Lili Jiang, Ming Li, Shan Ding, Baokai Xia, Chi Cheng, Jingjing Duan, Sheng Chen
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引用次数: 0

摘要

封底图片:人们普遍认为,由于几何和电子交替(称为“催化剂尺寸效应”),减小颗粒尺寸(如厚度)可以增强催化剂的活性。然而,也有例外。在编号为CNL266的文章中,我们制作了两个不同厚度(134.846和1.97nm)的金属有机框架(MOFs)样品。与普遍预期相反,与小厚度MOF相比,大厚度MOF表现出优异的二氧化碳电还原活性。利用密度函数理论(DFT)计算,系统地研究了进一步的解释。这项工作的结果挑战了这一共同概念,这将为许多电化学系统的催化剂设计提供新的线索。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Back Cover Image: Carbon Neutralization, Volume 2, Issue 4, July 2023

Back Cover Image: Carbon Neutralization, Volume 2, Issue 4, July 2023

Back cover image: It is common expectation that decreasing particle size (like thickness) can enhance the activities of catalysts due to geometric and electronic alternations (known as the “catalyst size effect”). However, there are exceptions. In article number CNL266, we have fabricated two metal-organic frameworks (MOFs) sample with different thickness (134.846 and 1.97 nm). In contrast to common expectations, large-thickness MOF has exhibited superior carbon dioxide electroreduction activities as comparison to small-thickness counterpart. Further explanations have been studied systematically by using density function theory (DFT) calculations. The results of this work have challenged the common concept, which would provide new clues for catalyst design toward a number of electrochemical systems.

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