E. Yu. Safronova, O. V. Korchagin, V. A. Bogdanovskaya, A. B. Yaroslavtsev
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Chemical Stability of Hybrid Materials Based on Nafion® Membrane and Hydrated Oxides
Improvement of the chemical stability of hybrid membranes based on perfluorosulfonic acid polymers is necessary to increase the lifetime of fuel cells. This article presents the results of the study of the transport properties and chemical stability of the hybrid Nafion® 212 membranes modified with nanoparticles of hydrated oxides SiO2, ZrO2, and TiO2 by in situ procedure. The influence of the nature of the dopant on the properties of the obtained materials is shown. The chemical degradation of the initial and hybrid membranes has been studied ex situ by treatment with Fenton’s reagent for 240 hours. The stability of materials increases in the series Nafion + SiO2 < Nafion + ZrO2 < Nafion < Nafion + TiO2. For the Nafion + TiO2 membrane the change in mass as a result of treatment with Fenton’s reagent is two times lower than for the initial Nafion membrane. This reveals an increase in the chemical stability of materials upon the incorporation of TiO2 nanoparticles due to their ability to bind free radicals. The maximum power of membrane-electrode assembly based on hybrid membranes containing TiO2 and SiO2 is higher than that based on Nafion® 212 by 7–10% at RH ~ 100% and t = 65°C.
期刊介绍：
The journal Membranes and Membrane Technologies publishes original research articles and reviews devoted to scientific research and technological advancements in the field of membranes and membrane technologies, including the following main topics:novel membrane materials and creation of highly efficient polymeric and inorganic membranes;hybrid membranes, nanocomposites, and nanostructured membranes;aqueous and nonaqueous filtration processes (micro-, ultra-, and nanofiltration; reverse osmosis);gas separation;electromembrane processes and fuel cells;membrane pervaporation and membrane distillation;membrane catalysis and membrane reactors;water desalination and wastewater treatment;hybrid membrane processes;membrane sensors;membrane extraction and membrane emulsification;mathematical simulation of porous structures and membrane separation processes;membrane characterization;membrane technologies in industry (energy, mineral extraction, pharmaceutics and medicine, chemistry and petroleum chemistry, food industry, and others);membranes and protection of environment (“green chemistry”).The journal has been published in Russian already for several years, English translations of the content used to be integrated in the journal Petroleum Chemistry. This journal is a split off with additional topics.
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