I. Raimondi, V. Rodrigues, J. Z. Lima, J. P. Marques, L. A. A. Vaz, E. M. Vieira
{"title":"利用热带泥炭作为当地替代材料吸附铅、锌和镉的评估:平衡研究","authors":"I. Raimondi, V. Rodrigues, J. Z. Lima, J. P. Marques, L. A. A. Vaz, E. M. Vieira","doi":"10.15446/ESRJ.V25N1.84276","DOIUrl":null,"url":null,"abstract":"How to cite item Raimondi, I. M., Silvestre-Rodrigues, V. G., Zanin-Lima, J., Pelinson-Marques, J., Artimonte-Vaz, L. A., & Vieira, E. M. (2021). Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study. Earth Sciences Research Journal, 25(1), pending pages. DOI: https://doi.org/10.15446/esrj.v25n1.84276 Peat is an organic material that has been widely used as an efficient and low-cost adsorbent. As many studies tend to focus on temperate peats, there is a lack of knowledge about the adsorption mechanism of tropical peats. This paper investigates the use of two Brazilian peats (Cravinhos C and Luis Antônio LA) from the Mogi-Guaçu river basin for the adsorption of lead (Pb), zinc (Zn), and cadmium (Cd), in order to contribute to the use of local and easy access materials to remediate contaminated sites. The peats adsorbed a high percentage of cations, especially Pb cations (100.0-46.3%), with commercial peat C showing higher adsorption than peat LA. The removal order was Pb2+ > Cd2+ ≥ Zn2+ for C and Pb2+ > Zn2+ > Cd2+ for LA. The batch data for both peats and for all metals were better fit by the Langmuir isotherm, with adsorption capacities (qm) for Pb, Zn, and Cd of 37.3134, 29.0674 and 21.2890 mmol kg-1 in peat C and 21.7391, 14.2550 and 3.6460 mmol kg-1 in LA, respectively, values comparable to those of other peats and biosorbents. The studied peats are considered efficient, alternative and low-cost adsorptive materials for these metals. The proximity of peatlands to areas with high potential for contamination necessitates the use of local materials to reduce remediation costs. ABSTRACT Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study","PeriodicalId":11456,"journal":{"name":"Earth Sciences Research Journal","volume":"25 1","pages":""},"PeriodicalIF":0.7000,"publicationDate":"2021-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study\",\"authors\":\"I. Raimondi, V. Rodrigues, J. Z. Lima, J. P. Marques, L. A. A. Vaz, E. M. Vieira\",\"doi\":\"10.15446/ESRJ.V25N1.84276\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"How to cite item Raimondi, I. M., Silvestre-Rodrigues, V. G., Zanin-Lima, J., Pelinson-Marques, J., Artimonte-Vaz, L. A., & Vieira, E. M. (2021). Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study. Earth Sciences Research Journal, 25(1), pending pages. DOI: https://doi.org/10.15446/esrj.v25n1.84276 Peat is an organic material that has been widely used as an efficient and low-cost adsorbent. As many studies tend to focus on temperate peats, there is a lack of knowledge about the adsorption mechanism of tropical peats. This paper investigates the use of two Brazilian peats (Cravinhos C and Luis Antônio LA) from the Mogi-Guaçu river basin for the adsorption of lead (Pb), zinc (Zn), and cadmium (Cd), in order to contribute to the use of local and easy access materials to remediate contaminated sites. The peats adsorbed a high percentage of cations, especially Pb cations (100.0-46.3%), with commercial peat C showing higher adsorption than peat LA. The removal order was Pb2+ > Cd2+ ≥ Zn2+ for C and Pb2+ > Zn2+ > Cd2+ for LA. The batch data for both peats and for all metals were better fit by the Langmuir isotherm, with adsorption capacities (qm) for Pb, Zn, and Cd of 37.3134, 29.0674 and 21.2890 mmol kg-1 in peat C and 21.7391, 14.2550 and 3.6460 mmol kg-1 in LA, respectively, values comparable to those of other peats and biosorbents. The studied peats are considered efficient, alternative and low-cost adsorptive materials for these metals. The proximity of peatlands to areas with high potential for contamination necessitates the use of local materials to reduce remediation costs. ABSTRACT Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study\",\"PeriodicalId\":11456,\"journal\":{\"name\":\"Earth Sciences Research Journal\",\"volume\":\"25 1\",\"pages\":\"\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2021-04-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Earth Sciences Research Journal\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://doi.org/10.15446/ESRJ.V25N1.84276\",\"RegionNum\":4,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"GEOSCIENCES, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Earth Sciences Research Journal","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.15446/ESRJ.V25N1.84276","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"GEOSCIENCES, MULTIDISCIPLINARY","Score":null,"Total":0}
Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study
How to cite item Raimondi, I. M., Silvestre-Rodrigues, V. G., Zanin-Lima, J., Pelinson-Marques, J., Artimonte-Vaz, L. A., & Vieira, E. M. (2021). Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study. Earth Sciences Research Journal, 25(1), pending pages. DOI: https://doi.org/10.15446/esrj.v25n1.84276 Peat is an organic material that has been widely used as an efficient and low-cost adsorbent. As many studies tend to focus on temperate peats, there is a lack of knowledge about the adsorption mechanism of tropical peats. This paper investigates the use of two Brazilian peats (Cravinhos C and Luis Antônio LA) from the Mogi-Guaçu river basin for the adsorption of lead (Pb), zinc (Zn), and cadmium (Cd), in order to contribute to the use of local and easy access materials to remediate contaminated sites. The peats adsorbed a high percentage of cations, especially Pb cations (100.0-46.3%), with commercial peat C showing higher adsorption than peat LA. The removal order was Pb2+ > Cd2+ ≥ Zn2+ for C and Pb2+ > Zn2+ > Cd2+ for LA. The batch data for both peats and for all metals were better fit by the Langmuir isotherm, with adsorption capacities (qm) for Pb, Zn, and Cd of 37.3134, 29.0674 and 21.2890 mmol kg-1 in peat C and 21.7391, 14.2550 and 3.6460 mmol kg-1 in LA, respectively, values comparable to those of other peats and biosorbents. The studied peats are considered efficient, alternative and low-cost adsorptive materials for these metals. The proximity of peatlands to areas with high potential for contamination necessitates the use of local materials to reduce remediation costs. ABSTRACT Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study
期刊介绍:
ESRJ publishes the results from technical and scientific research on various disciplines of Earth Sciences and its interactions with several engineering applications.
Works will only be considered if not previously published anywhere else. Manuscripts must contain information derived from scientific research projects or technical developments. The ideas expressed by publishing in ESRJ are the sole responsibility of the authors.
We gladly consider manuscripts in the following subject areas:
-Geophysics: Seismology, Seismic Prospecting, Gravimetric, Magnetic and Electrical methods.
-Geology: Volcanology, Tectonics, Neotectonics, Geomorphology, Geochemistry, Geothermal Energy, ---Glaciology, Ore Geology, Environmental Geology, Geological Hazards.
-Geodesy: Geodynamics, GPS measurements applied to geological and geophysical problems.
-Basic Sciences and Computer Science applied to Geology and Geophysics.
-Meteorology and Atmospheric Sciences.
-Oceanography.
-Planetary Sciences.
-Engineering: Earthquake Engineering and Seismology Engineering, Geological Engineering, Geotechnics.