发展玄武岩纤维改性原理提高其在交通建设中的应用效率

O. Doroshenko
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引用次数: 0

摘要

本文考察了玄武岩纤维作为一种有前途的材料的实验和理论依据,有助于获得一类新的建筑材料。结果,确定了温度的增加有助于纤维的耐碱性的增加。28天后在碱性溶液中老化期间的质量损失约为5%,而初始纤维在此期间损失超过纤维质量的30%。由于纤维的耐碱性降低和经济上不可行,进一步提高等温老化的温度是无效的。为了解释纤维在热处理过程中发生的结构过程,获得了原始纤维和热处理纤维的X射线图像和光谱。在300℃至500℃的热处理过程中,Fe+2会导致纤维的缺陷愈合、化学成分和表面结构发生变化→ Fe+3氧化和氧化铁四面体[FeO4]Na的形成,碱性阳离子对纤维表面的吸引力。证实了在500℃温度下对玄武岩纤维进行热处理的方便性,这导致了纤维结构的压实,并有助于提高其耐碱性,在水泥砂浆中老化的热处理玄武岩纤维表面的形态结构特征证实了这一点。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
DEVELOPMENT OF THE PRINCIPLES OF BASALT FIBER MODIFICATION WITH THE PURPOSE OF INCREASING THE EFFICIENCY OF ITS APPLICATION IN TRANSPORT CONSTRUCTION
The article examines the experimental and theoretical justification of the use of basalt fiber, as a promising material, with the help of which it is possible to obtain a new class of building materials. As a result, it was established that an increase in temperature contributes to an increase in alkali resistance of the fiber. The mass loss during aging in an alkaline solution after 28 days is about 5%, while the initial fiber loses more than 30% of the fiber mass during this time. A further increase in the temperature of isothermal aging is not effective due to a decrease in alkali resistance of the fibers and economic impracticability. To explain the processes occurring in the structure of the fiber during its heat treatment, X-ray images and spectra of the original and heat-treated fiber were obtained. In the process of heat treatment from 300 to 500 0С, the processes of defect healing, changes in the chemical composition and surface structure of the fibers occur as a result of Fe+2 → Fe+3 oxidation and the formation of iron oxide tetrahedra [FeO4]Na with the attraction of alkaline cations to the surface of the fibers. The expediency of thermal treatment of basalt fiber at a temperature of 500 0C is substantiated, which leads to compaction of the fiber structure and contributes to increasing its alkali resistance, which is confirmed by the morphostructural features of the surface of heat-treated basalt fiber aged in cement mortar.
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