二氧化钛:铽+球形纳米颗粒的快速合成及其光致发光性能

Murad M. A. Abualrejal, H. Zou, Jie Chen, Yanhua Song, Ye Sheng
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引用次数: 1

摘要

功能性光致发光材料的可控合成由于其迷人的光学性质而引起特别的兴趣。本文采用简单的溶胶-凝胶法制备了高度均匀的SiO2:xTb3+球形纳米颗粒。利用TEM、SEM、EDX、XRD、XPS和发光光谱对As制备的样品的结构、形貌、组成和发光性能进行了研究。SiO2:xTb3+球形纳米颗粒的PL强度是Tb3+离子浓度依赖性的,在Tb3+为3mol%时达到最大值。特别地,SiO2:xTb3+球形纳米颗粒表现出对应于5D4的绿色发射→Tb3+的7Fj跃迁(541nm)。这些结果表明,As制备的磷光体可能在固态照明领域找到潜在的应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A Facile Synthesis and Photoluminescence Properties of SiO 2 :Tb 3+ Spherical Nanoparticles
Controlled synthesis of functional photoluminescent materials are of particular interest due to their fascinating optical properties. Herein, highly uniform SiO2:xTb3+spherical nanoparticles are fabricated by a facile sol-gel method. The structure, morphology, compositions, and luminescence properties of As-prepared samples were well investigated using TEM, SEM, EDX, XRD, XPS and luminescence spectroscopy. The PL intensity of SiO2:xTb3+spherical nanoparticles is Tb3+ ions concentration dependent achieved a maximum at 3 mol % of Tb3+. Particularly, SiO2:xTb3+spherical nanoparticles exhibit a green emission corresponding to 5D4→7Fj transition (541 nm) of Tb3+. These results show that As-prepared phosphors may find potential application in solid-state lighting fields.
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