K. Sadowska, Paweł Awramiuk, I. Zgłobicka, K. Rećko, J. Zmojda
{"title":"用于紫外传感的掺铕LaPO4荧光粉的量子效率","authors":"K. Sadowska, Paweł Awramiuk, I. Zgłobicka, K. Rećko, J. Zmojda","doi":"10.4302/plp.v14i2.1146","DOIUrl":null,"url":null,"abstract":"The radiation conversion phenomenon is used for UV sensing applications with rare earth doped phosphors. This paper presents the results of structural and optical measurements of undoped and europium doped LaPO4 phosphors. LaPO4 phosphors with 1% mol, 2% mol, and 5% mol of europium were fabricated by the co-precipitation method. The effect of Eu3+ concentrations on the luminescence characteristics under UV LED excitation was investigated. The maximum quantum efficiency of luminescence (c.a. 82%) was obtained in sampled doped with 5% of europium. Full Text: PDF ReferencesM. Runowski, \"Nanotechnologia – nanomateriały, nanocząstki i wielofunkcyjne nanostruktury typu rdzeń/powłoka\", Chemik 68, 9, 766-775 (2014). DirectLink J. Zhou, J.L. Leano Jr., Z. Liu, D. Jin, K.-L. Wong, R.S. Liu, et al., \"Impact of Lanthanide Nanomaterials on Photonic Devices and Smart Applications\", Small 14, 1801882 (2018). CrossRef Z. Li, Y. Zhang, G. Han, \"Lanthanide-Doped Upconversion Nanoparticles for Imaging-Guided Drug Delivery and Therapy\", Springer Series in Biomater. Sci. Eng. 6, 139-164, (2016). CrossRef M. Lin, Y. Zhao, S. Wang, M. Liu, Z. Duan, Y. Chen, et al., \"Recent advances in synthesis and surface modification of lanthanide-doped upconversion nanoparticles for biomedical applications\", Biotechnol. Adv. 30, 1551-1561 (2012). CrossRef H. Su, Y. Nie, H. Yang, D. Tang, K. Chen, T. Zhang, \"Improving the thermal stability of phosphor in a white light-emitting diode (LED) by glass-ceramics: Effect of Al2O3 dopant\", J. Eur. Ceram. Soc. 38, 2005-2009 (2018). CrossRef J. Huang, X. Hu, J. Shen, D. Wu, C. Yin, R. Xiang, et al., \"Facile synthesis of a thermally stable Ce3+:Y3Al5O12 phosphor-in-glass for white LEDs\", Cryst. Eng. Comm 17, 7079-7085 (2015). CrossRef R. Zhang, H. Lin, Y. Yu, D. Chen, J. Xu, Y. Wang, \"A new-generation color converter for high-power white LED: transparent Ce3+:YAG phosphor-in-glass\", Laser Photon. Rev. 8, 158-164 (2014). CrossRef B. Zheng, Y. Bai, H. Chen, H. Pan, W. Ji, X. Gong, et al., \"Near-Infrared Light-Excited Upconverting Persistent Nanophosphors in Vivo for Imaging-Guided Cell Therapy\", ACS Appl. Mater. Interfaces 10, 19514 (2018). CrossRef J. Qiao, G. Zhou, Y. Zhou, Q. Zhang, Z. Xia, \"Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodes\", Nature Communications 10 (1), 5267 (2019). CrossRef V. Singh, A. Kumar, C. Mehare, H. Jeong, S. Dhoble, \"UV/VUV excited photoluminescence of Tb3+ doped LaPO4 green emitting phosphors for PDP applications\", Optik 206, 163733 (2020). CrossRef G. Han, Y. Wang, C. Wu, J. Zhang, \"Hydrothermal synthesis and vacuum ultraviolet-excited luminescence properties of novel Dy3+-doped LaPO4 white light phosphors\", Mat. Res. Bull. 44 (12), 2255-2257 (2009). CrossRef K. S. Gupta, P. S. Ghosh, M. Sahu, K. Bhattacharyya, R. Tewari, V. Natarajan, \"Intense red emitting monoclinic LaPO4:Eu3+ nanoparticles: host–dopant energy transfer dynamics and photoluminescence properties\", RSC Adv. 5, 58832-58842 (2015). CrossRef","PeriodicalId":20055,"journal":{"name":"Photonics Letters of Poland","volume":" ","pages":""},"PeriodicalIF":0.5000,"publicationDate":"2022-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Quantum efficiency of europium doped LaPO4 phosphors for UV sensing applications\",\"authors\":\"K. Sadowska, Paweł Awramiuk, I. Zgłobicka, K. Rećko, J. Zmojda\",\"doi\":\"10.4302/plp.v14i2.1146\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The radiation conversion phenomenon is used for UV sensing applications with rare earth doped phosphors. This paper presents the results of structural and optical measurements of undoped and europium doped LaPO4 phosphors. LaPO4 phosphors with 1% mol, 2% mol, and 5% mol of europium were fabricated by the co-precipitation method. The effect of Eu3+ concentrations on the luminescence characteristics under UV LED excitation was investigated. The maximum quantum efficiency of luminescence (c.a. 82%) was obtained in sampled doped with 5% of europium. Full Text: PDF ReferencesM. Runowski, \\\"Nanotechnologia – nanomateriały, nanocząstki i wielofunkcyjne nanostruktury typu rdzeń/powłoka\\\", Chemik 68, 9, 766-775 (2014). DirectLink J. Zhou, J.L. Leano Jr., Z. Liu, D. Jin, K.-L. Wong, R.S. Liu, et al., \\\"Impact of Lanthanide Nanomaterials on Photonic Devices and Smart Applications\\\", Small 14, 1801882 (2018). CrossRef Z. Li, Y. Zhang, G. Han, \\\"Lanthanide-Doped Upconversion Nanoparticles for Imaging-Guided Drug Delivery and Therapy\\\", Springer Series in Biomater. Sci. Eng. 6, 139-164, (2016). CrossRef M. Lin, Y. Zhao, S. Wang, M. Liu, Z. Duan, Y. Chen, et al., \\\"Recent advances in synthesis and surface modification of lanthanide-doped upconversion nanoparticles for biomedical applications\\\", Biotechnol. Adv. 30, 1551-1561 (2012). CrossRef H. Su, Y. Nie, H. Yang, D. Tang, K. Chen, T. Zhang, \\\"Improving the thermal stability of phosphor in a white light-emitting diode (LED) by glass-ceramics: Effect of Al2O3 dopant\\\", J. Eur. Ceram. Soc. 38, 2005-2009 (2018). CrossRef J. Huang, X. Hu, J. Shen, D. Wu, C. Yin, R. Xiang, et al., \\\"Facile synthesis of a thermally stable Ce3+:Y3Al5O12 phosphor-in-glass for white LEDs\\\", Cryst. Eng. Comm 17, 7079-7085 (2015). CrossRef R. Zhang, H. Lin, Y. Yu, D. Chen, J. Xu, Y. Wang, \\\"A new-generation color converter for high-power white LED: transparent Ce3+:YAG phosphor-in-glass\\\", Laser Photon. Rev. 8, 158-164 (2014). CrossRef B. Zheng, Y. Bai, H. Chen, H. Pan, W. Ji, X. Gong, et al., \\\"Near-Infrared Light-Excited Upconverting Persistent Nanophosphors in Vivo for Imaging-Guided Cell Therapy\\\", ACS Appl. Mater. Interfaces 10, 19514 (2018). CrossRef J. Qiao, G. Zhou, Y. Zhou, Q. Zhang, Z. Xia, \\\"Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodes\\\", Nature Communications 10 (1), 5267 (2019). CrossRef V. Singh, A. Kumar, C. Mehare, H. Jeong, S. Dhoble, \\\"UV/VUV excited photoluminescence of Tb3+ doped LaPO4 green emitting phosphors for PDP applications\\\", Optik 206, 163733 (2020). CrossRef G. Han, Y. Wang, C. Wu, J. Zhang, \\\"Hydrothermal synthesis and vacuum ultraviolet-excited luminescence properties of novel Dy3+-doped LaPO4 white light phosphors\\\", Mat. Res. Bull. 44 (12), 2255-2257 (2009). CrossRef K. S. Gupta, P. S. Ghosh, M. Sahu, K. Bhattacharyya, R. Tewari, V. Natarajan, \\\"Intense red emitting monoclinic LaPO4:Eu3+ nanoparticles: host–dopant energy transfer dynamics and photoluminescence properties\\\", RSC Adv. 5, 58832-58842 (2015). 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引用次数: 2
摘要
辐射转换现象用于稀土掺杂荧光粉的紫外传感应用。本文介绍了未掺杂和掺铕的LaPO4荧光粉的结构和光学测量结果。采用共沉淀法制备了铕含量分别为1%、2%和5%的LaPO4荧光粉。研究了Eu3+浓度对紫外LED激发下发光特性的影响。在掺5%铕的样品中获得了最大的发光量子效率(约82%)。全文:PDF参考文献runnowski，“纳米技术- nanomateriały, nanocząstki i wielofunkcyjne nanostrucstructyu rdzeka /powłoka”，化学，68,9,766-775(2014)。周建军，李家良，刘志强，金德良。王瑞生，刘瑞生等，“镧系纳米材料对光子器件和智能应用的影响”，光子学报，14,181882(2018)。引用本文:李振华，张勇，韩刚，“镧系元素掺杂上转换纳米粒子在成像引导药物传递和治疗中的应用”，中国生物医学工程学报(自然科学版)。科学。工程学报，6,139-164，(2016)。引用本文:林明，赵艳，王生，刘明，段志刚，陈勇，等，“稀土掺杂上转化纳米粒子的合成及表面修饰研究进展”，生物技术，生物工程学报，30(2012):1551-1561。苏慧，聂勇，杨辉，唐德东，陈凯，张涛，“微晶玻璃陶瓷中Al2O3掺杂对白光发光二极管(LED)荧光粉热稳定性的影响”，j。陶瓷。学报，38,2005-2009(2018)。引用本文:黄军，胡晓明，沈军，吴德东，殷春春，向仁，等，“用于白光led的热稳定Ce3+:Y3Al5O12玻璃内磷的快速合成”，晶体学报。Eng。科学通报17,7079-7085(2015)。张瑞荣，林红华，于勇，陈东东，徐军，王勇，“高功率白光LED的新一代颜色转换器:透明Ce3+:YAG玻璃中磷”，激光光子。Rev. 8, 158-164(2014)。引用本文:郑斌，陈红红，陈红红，潘红红，纪伟，龚晓燕，等，“近红外光激发下的上转换纳米磷光体在体内成像引导细胞治疗中的应用”，中国生物医学工程学报。板牙。接口10,19514(2018)。引用本文:乔军，周国光，周勇，张强，夏忠，“二价铕掺杂的近红外发光荧光粉”，自然通讯，10(1)，5267(2019)。CrossRef V. Singh, A. Kumar, C. Mehare, H. Jeong, S. Dhoble，“Tb3+掺杂LaPO4绿色发光荧光粉的UV/VUV激发光致发光研究”，光子学报，207,33(2020)。引用本文:韩刚，王勇，吴春春，张军，“新型Dy3+掺杂LaPO4白光荧光粉的水热合成及真空紫外激发发光性能”，高分子学报，44(12)，2255-2257(2009)。[CrossRef] K. S. Gupta, P. S. Ghosh, M. Sahu, K. Bhattacharyya, R. Tewari, V. Natarajan，“强红色发光单斜LaPO4:Eu3+纳米粒子的光致发光动力学研究”，光子学报，5(5):532 - 538(2015)。CrossRef
Quantum efficiency of europium doped LaPO4 phosphors for UV sensing applications
The radiation conversion phenomenon is used for UV sensing applications with rare earth doped phosphors. This paper presents the results of structural and optical measurements of undoped and europium doped LaPO4 phosphors. LaPO4 phosphors with 1% mol, 2% mol, and 5% mol of europium were fabricated by the co-precipitation method. The effect of Eu3+ concentrations on the luminescence characteristics under UV LED excitation was investigated. The maximum quantum efficiency of luminescence (c.a. 82%) was obtained in sampled doped with 5% of europium. Full Text: PDF ReferencesM. Runowski, "Nanotechnologia – nanomateriały, nanocząstki i wielofunkcyjne nanostruktury typu rdzeń/powłoka", Chemik 68, 9, 766-775 (2014). DirectLink J. Zhou, J.L. Leano Jr., Z. Liu, D. Jin, K.-L. Wong, R.S. Liu, et al., "Impact of Lanthanide Nanomaterials on Photonic Devices and Smart Applications", Small 14, 1801882 (2018). CrossRef Z. Li, Y. Zhang, G. Han, "Lanthanide-Doped Upconversion Nanoparticles for Imaging-Guided Drug Delivery and Therapy", Springer Series in Biomater. Sci. Eng. 6, 139-164, (2016). CrossRef M. Lin, Y. Zhao, S. Wang, M. Liu, Z. Duan, Y. Chen, et al., "Recent advances in synthesis and surface modification of lanthanide-doped upconversion nanoparticles for biomedical applications", Biotechnol. Adv. 30, 1551-1561 (2012). CrossRef H. Su, Y. Nie, H. Yang, D. Tang, K. Chen, T. Zhang, "Improving the thermal stability of phosphor in a white light-emitting diode (LED) by glass-ceramics: Effect of Al2O3 dopant", J. Eur. Ceram. Soc. 38, 2005-2009 (2018). CrossRef J. Huang, X. Hu, J. Shen, D. Wu, C. Yin, R. Xiang, et al., "Facile synthesis of a thermally stable Ce3+:Y3Al5O12 phosphor-in-glass for white LEDs", Cryst. Eng. Comm 17, 7079-7085 (2015). CrossRef R. Zhang, H. Lin, Y. Yu, D. Chen, J. Xu, Y. Wang, "A new-generation color converter for high-power white LED: transparent Ce3+:YAG phosphor-in-glass", Laser Photon. Rev. 8, 158-164 (2014). CrossRef B. Zheng, Y. Bai, H. Chen, H. Pan, W. Ji, X. Gong, et al., "Near-Infrared Light-Excited Upconverting Persistent Nanophosphors in Vivo for Imaging-Guided Cell Therapy", ACS Appl. Mater. Interfaces 10, 19514 (2018). CrossRef J. Qiao, G. Zhou, Y. Zhou, Q. Zhang, Z. Xia, "Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodes", Nature Communications 10 (1), 5267 (2019). CrossRef V. Singh, A. Kumar, C. Mehare, H. Jeong, S. Dhoble, "UV/VUV excited photoluminescence of Tb3+ doped LaPO4 green emitting phosphors for PDP applications", Optik 206, 163733 (2020). CrossRef G. Han, Y. Wang, C. Wu, J. Zhang, "Hydrothermal synthesis and vacuum ultraviolet-excited luminescence properties of novel Dy3+-doped LaPO4 white light phosphors", Mat. Res. Bull. 44 (12), 2255-2257 (2009). CrossRef K. S. Gupta, P. S. Ghosh, M. Sahu, K. Bhattacharyya, R. Tewari, V. Natarajan, "Intense red emitting monoclinic LaPO4:Eu3+ nanoparticles: host–dopant energy transfer dynamics and photoluminescence properties", RSC Adv. 5, 58832-58842 (2015). CrossRef
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