{"title":"Ag(I)催化3-丁氧基丙烯与咪唑的氢胺化反应","authors":"L. A. Grishchenko, L. N. Parshina, B. A. Trofimov","doi":"10.1134/S0012500823600116","DOIUrl":null,"url":null,"abstract":"<p>It has been shown that imidazole adds to the triple bond of 3-butoxypropyne under the action of catalytic amounts (5 mol %) of silver salts to give a mixture of α and β isomers: 1-(3-butoxyprop-1-en-2-yl)-imidazole and 1-[(<i>Z</i>)-3-butoxyprop-1-en-1-yl)]-imidazole.</p>","PeriodicalId":530,"journal":{"name":"Doklady Chemistry","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2023-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ag(I)-Catalyzed Hydroamination of 3-Butoxypropyne with Imidazole\",\"authors\":\"L. A. Grishchenko, L. N. Parshina, B. A. Trofimov\",\"doi\":\"10.1134/S0012500823600116\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>It has been shown that imidazole adds to the triple bond of 3-butoxypropyne under the action of catalytic amounts (5 mol %) of silver salts to give a mixture of α and β isomers: 1-(3-butoxyprop-1-en-2-yl)-imidazole and 1-[(<i>Z</i>)-3-butoxyprop-1-en-1-yl)]-imidazole.</p>\",\"PeriodicalId\":530,\"journal\":{\"name\":\"Doklady Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2023-05-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Doklady Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0012500823600116\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Doklady Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0012500823600116","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Ag(I)-Catalyzed Hydroamination of 3-Butoxypropyne with Imidazole
It has been shown that imidazole adds to the triple bond of 3-butoxypropyne under the action of catalytic amounts (5 mol %) of silver salts to give a mixture of α and β isomers: 1-(3-butoxyprop-1-en-2-yl)-imidazole and 1-[(Z)-3-butoxyprop-1-en-1-yl)]-imidazole.
期刊介绍:
Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.