由1,10-菲罗啉和两个羧酸盐配体构建的新型铅(II)配合物的合成和晶体结构

IF 1.8 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Main Group Metal Chemistry Pub Date : 2021-01-01 DOI:10.1515/mgmc-2021-0019

Lu-Lin Zhang, Shida Tang, Deliang Li, Yuanzheng Cheng, Liping Zhang

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引用次数: 3

摘要

摘要制备了铅(II)配合物[Pb(phen)(4-NB)(CH3COO)]，通过元素分析、FT-IR和单晶x射线分析对其进行了表征，其中phen = 1,10-菲罗啉，4-NB = 4-硝基苯甲酸酯。单晶x射线分析表明，该配合物为单体，包含两个羧酸配体，呈半定向结构。它通过分子间C−H⋯O氢键、π -π相互作用和次级Pb⋯O相互作用进一步延伸，形成二维超分子结构。

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Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands

Abstract The complex [Pb(phen)(4-NB)(CH3COO)] of lead(II) was prepared and characterized by means of elemental analysis, FT-IR, and single crystal X-ray analysis, where phen = 1,10-phenanthroline, 4-NB = 4-nitrobenzoate. The single crystal X-ray analysis indicates that the complex is a monomeric species, including two carboxylate ligands, and adopts a hemidirected structure. It is further extended by intermolecular C−H⋯O hydrogen bonds, π–π interactions and secondary Pb⋯O interactions to form two-dimensional supramolecular architecture.

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来源期刊

Main Group Metal Chemistry CHEMISTRY, INORGANIC & NUCLEAR-CHEMISTRY, ORGANIC

CiteScore

4.10

自引率

27.80%

发文量

审稿时长

4 weeks

期刊介绍： This journal is committed to the publication of short communications, original research, and review articles within the field of main group metal and semi-metal chemistry, Main Group Metal Chemistry is an open-access, peer-reviewed journal that publishes in ongoing way. Papers addressing the theoretical, spectroscopic, mechanistic and synthetic aspects of inorganic, coordination and organometallic main group metal and semi-metal compounds, including zinc, cadmium and mercury are welcome. The journal also publishes studies relating to environmental aspects of these metals, their toxicology, release pathways and fate. Articles on the applications of main group metal chemistry, including in the fields of polymer chemistry, agriculture, electronics and catalysis, are also accepted.