{"title":"类锂离子(氩到铀)核激发1s2l2l′态的能级","authors":"V. Yerokhin, A. Surzhykov","doi":"10.1063/1.5034574","DOIUrl":null,"url":null,"abstract":"Energy levels and fine-structure intervals of the $1s2l2l'$ core-excited states are calculated for ions along the Li isoelectronic sequence from argon to uranium. The calculation is performed by the relativistic configuration-interaction method adapted for treatment of autoionizing core-excited states. The calculational approach includes the relativistic treatment of the nuclear recoil effect, the leading QED shifts as delivered by the model QED operator, and the frequency dependence of the Breit interaction. The $1s2l2l'-1s^22l$ transition energies are obtained by combining the present results for the $1s2l2l'$ states with energies of the $1s^22l$ states compiled from previous calculations. All theoretical energies are supplied with uncertainty estimates. Our theoretical predictions for the $1s2l2l'-1s^22l$ transitions are significantly more accurate than the best experimental results available today and can be used for calibrating experimental X-ray spectra.","PeriodicalId":16783,"journal":{"name":"Journal of Physical and Chemical Reference Data","volume":" ","pages":""},"PeriodicalIF":4.4000,"publicationDate":"2018-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1063/1.5034574","citationCount":"26","resultStr":"{\"title\":\"Energy Levels of Core-Excited 1s2l2l′ States in Lithium-Like Ions: Argon to Uranium\",\"authors\":\"V. Yerokhin, A. Surzhykov\",\"doi\":\"10.1063/1.5034574\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Energy levels and fine-structure intervals of the $1s2l2l'$ core-excited states are calculated for ions along the Li isoelectronic sequence from argon to uranium. The calculation is performed by the relativistic configuration-interaction method adapted for treatment of autoionizing core-excited states. The calculational approach includes the relativistic treatment of the nuclear recoil effect, the leading QED shifts as delivered by the model QED operator, and the frequency dependence of the Breit interaction. The $1s2l2l'-1s^22l$ transition energies are obtained by combining the present results for the $1s2l2l'$ states with energies of the $1s^22l$ states compiled from previous calculations. All theoretical energies are supplied with uncertainty estimates. Our theoretical predictions for the $1s2l2l'-1s^22l$ transitions are significantly more accurate than the best experimental results available today and can be used for calibrating experimental X-ray spectra.\",\"PeriodicalId\":16783,\"journal\":{\"name\":\"Journal of Physical and Chemical Reference Data\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2018-05-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1063/1.5034574\",\"citationCount\":\"26\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Physical and Chemical Reference Data\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1063/1.5034574\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Physical and Chemical Reference Data","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1063/1.5034574","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Energy Levels of Core-Excited 1s2l2l′ States in Lithium-Like Ions: Argon to Uranium
Energy levels and fine-structure intervals of the $1s2l2l'$ core-excited states are calculated for ions along the Li isoelectronic sequence from argon to uranium. The calculation is performed by the relativistic configuration-interaction method adapted for treatment of autoionizing core-excited states. The calculational approach includes the relativistic treatment of the nuclear recoil effect, the leading QED shifts as delivered by the model QED operator, and the frequency dependence of the Breit interaction. The $1s2l2l'-1s^22l$ transition energies are obtained by combining the present results for the $1s2l2l'$ states with energies of the $1s^22l$ states compiled from previous calculations. All theoretical energies are supplied with uncertainty estimates. Our theoretical predictions for the $1s2l2l'-1s^22l$ transitions are significantly more accurate than the best experimental results available today and can be used for calibrating experimental X-ray spectra.
期刊介绍:
The Journal of Physical and Chemical Reference Data (JPCRD) is published by AIP Publishing for the U.S. Department of Commerce National Institute of Standards and Technology (NIST). The journal provides critically evaluated physical and chemical property data, fully documented as to the original sources and the criteria used for evaluation, preferably with uncertainty analysis. Critical reviews may also be included if they document a reference database, review the data situation in a field, review reference-quality measurement techniques, or review data evaluation methods.