准弹性中子散射光谱仪的分辨率强度优化

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2021-10-29 DOI:10.3233/jnr-210029

R. Zorn

{"title":"准弹性中子散射光谱仪的分辨率强度优化","authors":"R. Zorn","doi":"10.3233/jnr-210029","DOIUrl":null,"url":null,"abstract":"In quasieleastic neutron scattering spectrometers one usually faces a trade-off between energy resolution and counting statistics. If the resolution is improved the intensity at the detectors reduces and vice versa. It is not immediately clear how to weigh both factors against each other. In this paper it is proposed to use the maximum time obtainable by Fourier transform of the spectra as the quantity to be optimised. It is shown that this leads to a well-defined criterion for the choice of the resolution.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2021-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Resolution-intensity optimisation on quasielastic neutron scattering spectrometers\",\"authors\":\"R. Zorn\",\"doi\":\"10.3233/jnr-210029\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In quasieleastic neutron scattering spectrometers one usually faces a trade-off between energy resolution and counting statistics. If the resolution is improved the intensity at the detectors reduces and vice versa. It is not immediately clear how to weigh both factors against each other. In this paper it is proposed to use the maximum time obtainable by Fourier transform of the spectra as the quantity to be optimised. It is shown that this leads to a well-defined criterion for the choice of the resolution.\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2021-10-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3233/jnr-210029\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3233/jnr-210029","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

在准弹性中子散射光谱仪中，人们通常面临能量分辨率和计数统计之间的权衡。如果分辨率提高，探测器处的强度降低，反之亦然。目前还不清楚如何权衡这两个因素。本文提出用谱的傅里叶变换得到的最大时间作为优化量。结果表明，这导致了一个明确定义的分辨率选择标准。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Resolution-intensity optimisation on quasielastic neutron scattering spectrometers

In quasieleastic neutron scattering spectrometers one usually faces a trade-off between energy resolution and counting statistics. If the resolution is improved the intensity at the detectors reduces and vice versa. It is not immediately clear how to weigh both factors against each other. In this paper it is proposed to use the maximum time obtainable by Fourier transform of the spectra as the quantity to be optimised. It is shown that this leads to a well-defined criterion for the choice of the resolution.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.