铁配合物催化脱氢Sn-E（E=S，Se）键的形成

IF 1.1 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Heteroatom Chemistry Pub Date : 2018-12-04 DOI:10.1002/hc.21461

Masumi Itazaki, Yudai Ogawa, Wataru Nakamura, Hiroshi Nakazawa

引用次数: 0

摘要

研究了铁络合物催化氢锡烷与硫醇和硒醇脱氢形成Sn-E (E = S, Se)键。所有新化合物都通过H、C{H}、Se{H}和Sn{H}核磁共振测量和元素分析得到了完整的表征。用单晶法证实了1,1′-(1,3-二硫-2,2-二丁基斯坦基)-[3]二茂铁的结构

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Dehydrogenative Sn–E (E = S, Se) bond formation catalyzed by an iron complex

Iron complex-catalyzed dehydrogenative Sn–E (E = S, Se) bond formation of hydrostannane with thiol and selenol was achieved. All new compounds were fully characterized using ¹H, ¹³C{¹H}, ⁷⁷Se{¹H}, and ¹¹⁹Sn{¹H} NMR measurements and elemental analyses. The structure of 1,1′-(1,3-dithia-2,2-dibutylstanyl)-[3]ferrocenophane was confirmed by single-crystal X-ray diffraction.

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来源期刊

Heteroatom Chemistry 化学-化学综合

CiteScore

1.20

自引率

0.00%

发文量

审稿时长

6 months

期刊介绍： Heteroatom Chemistry brings together a broad, interdisciplinary group of chemists who work with compounds containing main-group elements of groups 13 through 17 of the Periodic Table, and certain other related elements. The fundamental reactivity under investigation should, in all cases, be concentrated about the heteroatoms. It does not matter whether the compounds being studied are acyclic or cyclic; saturated or unsaturated; monomeric, polymeric or solid state in nature; inorganic, organic, or naturally occurring, so long as the heteroatom is playing an essential role. Computational, experimental, and combined studies are equally welcome. Subject areas include (but are by no means limited to): -Reactivity about heteroatoms for accessing new products or synthetic pathways -Unusual valency main-group element compounds and their properties -Highly strained (e.g. bridged) main-group element compounds and their properties -Photochemical or thermal cleavage of heteroatom bonds and the resulting reactivity -Uncommon and structurally interesting heteroatom-containing species (including those containing multiple bonds and catenation) -Stereochemistry of compounds due to the presence of heteroatoms -Neighboring group effects of heteroatoms on the properties of compounds -Main-group element compounds as analogues of transition metal compounds -Variations and new results from established and named reactions (including Wittig, Kabachnik–Fields, Pudovik, Arbuzov, Hirao, and Mitsunobu) -Catalysis and green syntheses enabled by heteroatoms and their chemistry -Applications of compounds where the heteroatom plays a critical role. In addition to original research articles on heteroatom chemistry, the journal welcomes focused review articles that examine the state of the art, identify emerging trends, and suggest future directions for developing fields.