二氯二氧化-(4,4′-二甲基-2,2′-联吡啶基)钼(VI)的合成及x射线衍射数据

IF 0.3 4区材料科学 Q4 MATERIALS SCIENCE, CHARACTERIZATION & TESTING

Powder Diffraction Pub Date : 2023-02-20 DOI:10.1017/S0885715623000040

J. L. Pinto, H. Camargo, N. J. Castellanos

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引用次数: 0

摘要

以钼(VI)-二氧化二氯和4,4 ' -二甲基-2,2 ' -联吡啶为原料，在CH2Cl2中制备了二氧化二氯-(4,4 ' -二甲基-2,2 ' -联吡啶)-钼(VI)配合物，得到了透明的绿色溶液。用乙醚沉淀钼配合物，过滤分离，用乙醚洗涤浅绿色固体。XRPD图谱表明，该化合物属于单斜空间群P21/n (No.14)，其晶胞参数为a = 12.0225(8) Å， b = 10.3812(9) Å， c = 11.7823(9) Å， β = 103.180(9)°，晶胞体积V = 1431.79 Å3, Z = 4。

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Synthesis and X-ray diffraction data of dichloro-dioxido-(4,4′-dimethyl-2,2′-bipyridyl) molybdenum (VI)

The dichloro-dioxide-(4,4′-dimethyl-2,2′-bipyridyl)-molybdenum (VI) complex was prepared from molybdenum(VI)-dichloride-dioxide and 4,4′-dimethyl-2,2′-bipyridyl in CH2Cl2 obtaining a clear green solution. The molybdenum complex was precipitated using ethyl ether, separated by filtration and the light green solid washed with ethyl ether. The XRPD pattern for the new compound showed that the crystalline compound belongs to the monoclinic space group P21/n (No.14) with refined unit-cell parameters a = 12.0225(8) Å, b = 10.3812(9) Å, c = 11.7823(9) Å, β = 103.180(9)°, unit-cell volume V = 1431.79 Å3, and Z = 4.

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来源期刊

$Powder Diffraction$

Powder Diffraction 工程技术-材料科学：表征与测试

CiteScore

0.90

自引率

0.00%

发文量

审稿时长

>12 weeks

期刊介绍： Powder Diffraction is a quarterly journal publishing articles, both experimental and theoretical, on the use of powder diffraction and related techniques for the characterization of crystalline materials. It is published by Cambridge University Press (CUP) for the International Centre for Diffraction Data (ICDD).